Reaction of a preformed cluster [{(η5-C5Me5)WS3}3Cu7(MeCN)9](PF6)4 (1) in MeCN with LiCl and PPh3 gave rise to a tetranuclear cationic cluster [(η5-C5Me5)WS3{Cu(PPh3)}3Cl](PF6) (2). The title compound 2 was char...
Reaction of (NH4)2WOS3 with CuI and 4-tert-butylpyridine (4-bpy) in EtOH afforded a tetranuclear neutral cluster WOS3Cu3I(4-bpy)3·0.25EtOH. This compound was characterized by elementary analysis, IR, 1H NMR, TGA, and...