Thermoregulated Organic Biphasic Hydrogenation of 1-Octene Catalyzed by Ru/PETPP Complex  

作　　者：Ya Dong LU Yan Hua WANG Zi Lin JIN 

机构地区：[1]State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012

出　　处：《Chinese Chemical Letters》2006年第2期255-257,共3页中国化学快报（英文版）

基　　金：the financial support from the National Natural Science Foundation of China （Grant no. 20376013）; the Fok Ying Tung Education Foundation （Grant no. 91071） ;the Doctorate Program Foundation of Higher Education （Grant no. 20020141004）.

摘　　要：Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether （TGME） and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions： P（H2）=5.0MPa, T=80℃, t=3h, 1-octene/Ru=1000 （molar ratio）, the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether （TGME） and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions： P（H2）=5.0MPa, T=80℃, t=3h, 1-octene/Ru=1000 （molar ratio）, the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.

关 键 词：Thermoregulated organic biphasic system HYDROGENATION 1-OCTENE ruthenium. 

分 类 号：O623.11[理学—有机化学] O623.121[理学—化学]