Rhodium-catalyzed Asymmetric Ring Opening Reaction of Oxabenzo-norbornadiene with Substituted Phenolic Nucleophiles  

Rhodium-catalyzed Asymmetric Ring Opening Reaction of Oxabenzo-norbornadiene with Substituted Phenolic Nucleophiles

在线阅读下载全文

作  者:Ying Feng HAN Ding Qiao YANG Er Chang LIU Jian Xia DONG 

机构地区:[1]College of Chemistry and Environment, South China Normal University, Guangzhou 510006

出  处:《Chinese Chemical Letters》2006年第3期296-298,共3页中国化学快报(英文版)

基  金:the Natural Science Foundation of Guangdong Province for financial support (No.04010404).

摘  要:We have developed an asymmetric ring opening reaction of oxabenzonorbornadienes with substituted phenolic nucleophiles. Under the reaction conditions ( [Rh(COD)C1]2 (1 mol%), (S)-(R)-PPF-P^Bu2 (2 mol%), THF, reflux), the reaction products were obtained with high yield and enantiomeric excesses ( up to 99% ee).We have developed an asymmetric ring opening reaction of oxabenzonorbornadienes with substituted phenolic nucleophiles. Under the reaction conditions ( [Rh(COD)C1]2 (1 mol%), (S)-(R)-PPF-P^Bu2 (2 mol%), THF, reflux), the reaction products were obtained with high yield and enantiomeric excesses ( up to 99% ee).

关 键 词:Asymmetric ring opening RHODIUM-CATALYZED oxabenzonorbornadienes. 

分 类 号:O626.3[理学—有机化学] O621.3[理学—化学]

 

参考文献:

正在载入数据...

 

二级参考文献:

正在载入数据...

 

耦合文献:

正在载入数据...

 

引证文献:

正在载入数据...

 

二级引证文献:

正在载入数据...

 

同被引文献:

正在载入数据...

 

相关期刊文献:

正在载入数据...

相关的主题
相关的作者对象
相关的机构对象