云南高校图书馆联盟文献共享服务平台- RHODIUM-CATALYZED

RHODIUM-CATALYZED: 作品数：38被引量：19H指数：2; 导出分析报告; 相关领域：理学更多>>; 相关作者：许斌钱光印刘秉新蓝宇祝勇更多>>; 相关机构：上海大学河南科技学院重庆大学浙江理工大学更多>>; 相关期刊：《Science China Chemistry》《China Petroleum Processing & Petrochemical Technology》《Chinese Journal of Chemistry》《Organic Chemistry Frontiers》更多>>; 相关基金：国家自然科学基金广东省自然科学基金天津市自然科学基金中国科学院“百人计划”更多>>

Rhodium-Catalyzed C(sp^(3))–H Arylation of 8-Methylquinolines with Arylsilanes: 《Chinese Journal of Chemistry》2024年第21期2627-2632,共6页Lin Li Haidong Liu Yupeng Qian Guohong Shen Yun Shi Jiajie Du Haiqing Luo; supported by the National Natural Science Foundation of China(22271062);Doctoral Scientific Research Foundation of Gannan Normal University(BSJJ202303).; We herein describe a Cp^(*)Rh^(Ⅲ)-catalyzed C(sp^(3))–H mono-arylation of 8-methylquinolines with benign arylsilanes.The use of 1-adamantane carboxylic acid can benefit the efficiency in this transformation,and AgF ...; 关键词：C(sp^(3))-H arylation C-H activation ARYLSILANES CROSS-COUPLING Nitrogen heterocycles

Rhodium-Catalyzed Asymmetric Hydrogenation of Tetrasubstitutedα,β-Unsaturated Amides:Efficient Access to Chiralβ-Amino Amides: 《Chinese Journal of Chemistry》2024年第21期2641-2646,共6页Bing Jiao Fangyuan Wang Hui Lv; financial support from the National Natural Science Foundation of China(Grant Nos.22071188,22371217);Hubei Provincial Natural Science Foundation of China(2023AFA011).; The first asymmetric hydrogenation of acyclic tetrasubstitutedα,β-unsaturated amides has been achieved by using Rh/DuanPhos complex as a catalyst,delivering chiralβ-amino amides with two contiguous chiral centers i...; 关键词：Asymmetric hydrogenation β-Amino amides Asymmetric catalysis Contiguous chiral centers RHODIUM AMINES Reduction ENANTIOSELECTIVITY

Rhodium-catalyzed enantioselective in situ C(sp^(3))-H heteroarylation by a desymmetrization approach: 《Chinese Chemical Letters》2024年第10期218-222,共5页Yujia Shi Yan Qiao Pengfei Xie Miaomiao Tian Xingwei Li Junbiao Chang Bingxian Liu; financial support for this work from the National Key R&D Program of China(No.2021YFC0864700);the National Natural Science Foundation of China(Nos.21801066,U1804283 and 82130103);the Central Plains Scholars and Scientists Studio Fund(No.2018002);the project funded by the Natural Science Foundation of Henan(Nos.222300420056,222300420204);the China Postdoctoral Science Foundation(Nos.2020M682307,2021T140183)。; A rhodium-catalyzed desymmetrization reaction for enantioselective methyl C-H arylation is achieved by utilizing an in situ arylating reagent via nucleophilic cyclization of o-aminoaryl alkyne.The reaction results in ...; 关键词：Heteroarylation C(sp^(3))-H activation ENANTIOSELECTIVE DESYMMETRIZATION πInteractions

Multifunctional 2-(2-hydroxyphenyl)benzoxazoles: Ready synthesis,mechanochromism, fluorescence imaging, and OLEDs: 《Chinese Chemical Letters》2024年第10期223-227,共5页Kangmin Wang Liqiu Wan Jingyu Wang Chunlin Zhou Ke Yang Liang Zhou Bijin Li; Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology(No.BM2012110);the fundamental research funds for the central universities(No.2023CDJYGRH-YB17);the Venture&Innovation Support Program for Chongqing Overseas Returnees(No.cx2022061);the Natural Science Foundation of Chongqing(No.CSTB2022NSCQ-MSX1123);the Chongqing Talents:Exceptional Young Talents Project(No.cstc2021ycjh-bgzxm0067);Changzhou University,Advanced Catalysis and Green Manufacturing Collaborative Innovation Center(No.ACGM2022–10–10);National Natural Science Foundation of China(Nos.21702019,62174160)for financial support。; Triphenylamine(TPA)-containing 2-(2-hydroxyphenyl)benzoxazoles(2a-2c)have been synthesized via a highly efficient rhodium-catalyzed C–H/C–H cross-coupling reaction.Compound 2a is a novel mechanofluorochromic materia...; 关键词：RHODIUM-CATALYZED 2-(2'-Hydroxyphenyl)benzoxazoles Mechanochromism Fluorescence images OLEDS

Rhodium-Catalyzed Regioselective C-O and C-C Bonds Formation of 3-Oxopent-4-enenitriles with Alkynes for the Synthesis of Polysubstituted 2H-Pyrans: 《Chinese Journal of Chemistry》2024年第17期1986-1992,共7页Kelu Yan Xiao Liu Jiangwei Wen Qiuyun Li Junjie Wang Yang Zheng Xiu Wang; supported by the National Natural Science Foundation of China(No.22101152);the Youth Talent Program Startup Foundation of Qufu Normal University(No.614201);the School-Level Research Projects of Yancheng Institute of Technology(No.xjr2020044).; The rhodium-catalyzed C-H bond activation and cyclization of 3-oxopent-4-enenitriles with alkynes proceed efficiently.Various 2H-pyrans with multiple substituents are achieved in good yields through regioselective for...; 关键词：Rhodium/C-H activation 3-Oxopent-4-enenitriles ALKYNES 2H-Pyrans Transition metals Regioselectivity Cyclization Comprehensive Summary

Rhodium-Catalyzed N-Arylation Addition of Arylboronic Acids to Ketimines: 《Chinese Journal of Chemistry》2024年第18期2243-2248,共6页Xue-Wei Qian Xing-Wen Sun; financial support from the Natural Science Foundation of Shanghai(20zR1405500).; Herein,we report rhodium catalyzed N-arylation via addition of arylboronic acids to electron-deficientα-iminoesters which can be prepared in high efficiency by using easily accessible B-carbonyl esters.The reaction i...; 关键词：Rhodium catalyzed N-Arylation addition Amines UMPOLUNG INDOLE C-C coupling

Rhodium-Catalyzed Asymmetric Trifluoromethoxylation of Racemic Allylic Trichloroacetimidates: 《CCS Chemistry》2024年第8期1885-1894,共10页Liyan Wang Yafeng Si Yu-Xin Luan Pingping Tang; supported by the National Key Research and Development Program of China(grant no.2021YFF0701700);the National Natural Science Foundation of China(grant nos.21925105,92156001,and 22101141);the Natural Science Foundation of Tianjin(grant no.18JCJQJC47000);the Haihe Laboratory of Sustainable Chemical Transformations,and the Fundamental Research Funds for the Central Universities.; A rhodium/diene catalyzed asymmetric allylic trifluoromethoxylation reaction is reported,which afforded chiral trifluoromethoxylated allylic compounds in 52%–97%yields with up to 97%enantiomeric excess.These are the ...; 关键词：asymmetric trifluoromethoxylation trifluoromethyl arylsulfonates rhodium trichloroacetimidates chiral diene ligand

Rhodium-catalyzed Doyle-Kirmse rearrangement reactions of sulfoxoniun ylides: 《Chinese Chemical Letters》2024年第4期363-366,共4页Ying-Di Hao Zhi-Qian Lin Xiao-Yu Guo Jiao Liang Can-Kun Luo Qian-Tao Wang Li Guo Yong Wu; supported by Sichuan Science and Technology Program (No.2020YJ0221)。; Doyle-Kirmse rearrangement reactions have received continuous attention as an important method for constructing complex chemical structures. Herein, we disclosed an efficient rhodium-catalyzed DoyleKirmse rearrangemen...; 关键词：Sulfoxonium ylides Rhodium(Ⅱ)-catalyzed CARBENE Rearrangement reactions One-pot process

Rhodium-Catalyzed Asymmetric Transfer Hydrogenation of Heterocyclic Diaryl Ketones:Facile Access to Key Intermediate of Baloxavir: 《Chinese Journal of Chemistry》2024年第1期43-47,共5页Li Wang Renwei Xiao Jingyuan Song Long-Sheng Zheng Qiwei Lang Gen-Qiang Chen Xumu Zhang; the Southern University of Science and Technology(start-up fund),Shenzhen Science and Technology Innovation Committee(No.KQTD20150717103157174);Stable Support Plan Program of Shenzhen Natural Science Fund(Program Contract No.20200925161222002);Key-Area Research and DevelopmentPt rogramofGuangdong Province((No.2020B010188001);Innovative Team of Universities in Guangdong Province(No.2020KCXTD016);National Natural Science Foundation of China(No.21991113);the National Natural Science Foundation of China(No.22171129);Shenzhen Science and Technology Innovation Committee(JCYJ20210324104202007)for financial support.; Transition metal-catalyzed asymmetric transfer hydrogenation has been proven to be a powerful approach for the synthesis of chiral alcohols.Herein,a highly efficient and enantioselective transfer hydrogenation of dibe...; 关键词：Asymmetric transfer hydrogenation Baloxavir Chiral alcohol ENANTIOSELECTIVITY Heterocyclic diaryl ketone Rhodium(Ⅱ)

Rhodium-catalyzed enantioselective annulation of N-phenoxyacetamides with 1,3-dienes: 《Science China Chemistry》2023年第10期2842-2846,共5页Hui Yang Zi-Qi Yang Su-Zhen Zhang Wen-Wen Zhang Qing Gu Shu-Li You; supported by the National Key Research and Development Program of China(2021YFA1500100);the National Natural Science Foundation of China(21821002,92256302,22071260);the Science and Technology Commission of Shanghai Municipality(21520780100)。; Chiral dihydrobenzofuran is a valuable synthetic fragment in both medicinal and organic chemistry.Efficient rhodium(Ⅲ)-catalyzed chemoselective and enantioselective C-H functionalization/[3+2]annulation of N-phenoxya...; 关键词：asymmetric catalysis C-H functionalization rhodium catalysis chiral dihydrobenzofuran

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