Rhodium-Catalyzed N-Arylation Addition of Arylboronic Acids to Ketimines  

作　　者：Xue-Wei Qian Xing-Wen Sun 

机构地区：[1]Department of Chemistry,Fudan University,220 Handan Road,Shanghai 200433,China

出　　处：《Chinese Journal of Chemistry》2024年第18期2243-2248,共6页中国化学（英文版）

基　　金：financial support from the Natural Science Foundation of Shanghai(20zR1405500).

摘　　要：Herein,we report rhodium catalyzed N-arylation via addition of arylboronic acids to electron-deficientα-iminoesters which can be prepared in high efficiency by using easily accessible B-carbonyl esters.The reaction is highly regiospecific to achieve the N-aryl addition efficiently with up to 99%yield under mild conditions.The corresponding product can be further efficiently converted into indoles andaseries of other important building blocks.

关 键 词：Rhodium catalyzed N-Arylation addition Amines UMPOLUNG INDOLE C-C coupling 

分 类 号：O61[理学—无机化学]