毛细管气相色谱在工业分析中的应用（Ⅶ）──全烷基化β－环糊精毛细管柱的应用  

Application of Capillary Column Gas Chromatography in Industrial Analysis(Ⅶ) Analysis of Disubstituted Benzene isomers Using Peralkyl-β-Cyclodextrin as the Stationary Phases

作　　者：傅若农[1] 戴荣继[1] 周伟[1] 

机构地区：[1]北京理工大学化工与材料学院

出　　处：《北京理工大学学报》1996年第2期176-180,共5页Transactions of Beijing Institute of Technology

基　　金：国家自然科学基金;高等学校博士学科点专项基金

摘　　要：研究了以全烷基化β－环糊精毛细管柱分离二元取代苯异构体的方法．合成了全甲基化β－环糊精，全丙基化β－环糊精，全戊基化β－环糊精．并用它们作气相色谱固定液，涂渍在弹性石英毛细管柱上，用以分离二甲苯、二硝基甲苯、甲酚、二甲酸等工业及环境污染物中常见的异构体．用１０ｍ长的毛细管柱可以很好地分离上述的二元取代苯异构体．Describes a method of separation for disubstituted benzene isomers unsin capil lary columns coatal with peralkylated β-cyclodextrins. Three peralkylatedβ permethyl-i.e permethyl-, perpropel-and perpentyl0-β-cyclodextrins were synthesized, and the capillary columns were coated with there stationary phases. A number of disubstituted benzene isomers were separated using a 10m long column coated with these stationary phases, e. g. xylene, Crysol, dimethyphenol, diclorobenzene, nitrochlorobenzene, and nitrobromobenzene isomers.

关 键 词：烷基化 环糊精 毛细管 气相色谱 工业分析 

分 类 号：O657.71[理学—分析化学]