铯盐促进的有机反应  

Organic Reactions Promoted by Cesium Salts

作　　者：段新方[1] 张站斌[1] 

机构地区：[1]北京师范大学化学系,北京100875

出　　处：《有机化学》2006年第4期573-578,共6页Chinese Journal of Organic Chemistry

摘　　要：铯盐如Cs2CO3,CsF等因在钯催化碳碳偶联,N,O,S的烃基化反应中表现出良好的性能而引起了人们的广泛关注.介绍了铯盐在钯催化的Suzuki,Heck,Stille,Sonogashira反应,烯醇盐的芳基化,酚类的邻位芳基化以及羰基化反应中的促进作用.同时还对铯盐参与的N,O,S等的烃基化反应进行了讨论,并侧重于与其他碱金属盐的对比.Cesium salts such as Cs2CO3, CsF, etc. have attracted much attention for their good effect on promoting Pd-catalyzed C-C formation coupling, alkylation and arylation of N, O and S atoms. This paper introduces the salt assistance to Pd-catalyzed Suzuki, Heck, Stille and Sonogashira reactions as well as arylation of enolate, ortho-arylation of phenol and carbonylation. The Cs-mediated alkylation and arylation of N, O and S atoms are also discussed, with emphases placed upon the comparison of cesium salts with their potassium or sodium analogs.

关 键 词：铯盐 SUZUKI反应 Heck反应 Stille反应 Sonogashira反应 烷基化 芳基化 

分 类 号：O621.25[理学—有机化学] TQ426.94[理学—化学]