Synthesis and Unexpected Ring-opening Reaction of a New TADDOL Analogue with Chiral Cyclopropane Ring as Backbone  

作　　者：Jun LIU Qing Hua BIAN Ming An WANG Hong Chao GUO Min WANG 

机构地区：[1]Department of Applied Chemistry, China Agricultural University, Beijing 100094

出　　处：《Chinese Chemical Letters》2006年第5期606-608,共3页中国化学快报（英文版）

基　　金：founded by the National Natural Science Foundation of China(No.20472111).

摘　　要：Synthesis and ring-opening reaction of TADDOL analogue with cyclopropane as chiral backbone were described. A plausible ring-opening and carbonium ion rearrangement mechanism have been proposed.

关 键 词：TADDOL analogue RING-OPENING cyclopropane ring synthesis. tetraaryl-1 3-dioxolane-4 5-dimethanol 

分 类 号：O625.34[理学—有机化学]