financial support from National Natural Science Foundation of China(Nos.21801129,22078153 and22378201);National Key Research and Development Program of China(No.2022YFB3805603);Natural science research projects in Jiangsu Higher Education Institutions(No.18KJB150018);Open Research Fund of School of Chemistry and Chemical Engineering;Henan Normal University(No.2024Y16);Nanjing Tech University(Start-up Grant Nos.39837137,39837101 and 3827401739)for financial support。
Pyridyl-based ketones and 1,6-diketones are both attractive and invaluable scaffolds which play pivotal roles in the construction and structural modification of a plethora of synthetically paramount natural products,p...
the funding of the National Natural Science Foundation of China(22371269);the State Key Laboratory of Elementoorganic Chemistry Nankai University(202001);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0450301);the Open Project of Key Laboratory of Organosilicon Chemistry,and Material Technology of Ministry of Education,Hangzhou Normal University(KFJJ2022013);Anhui Provincial Major Science and Technology Project(2022e03020005).
Arylidenecyclopropanes(ACPs)are highly strained substrates that can be readily utilized for diverse transformations.This study showcases the outcomes of copper-catalyzed ring-opening hydrosilylation and hydroboration ...
This work was financially supported by the National Natural Science Foundation of China(Nos.52022031 and 21734004).
Organocatalysis has shown special potency for simplifying the construction of complex polymer structures.We are reporting here a one-pot synthetic pathway using amine as a selectivity-switching agent in the two-compon...
grateful for the financial support from the National Natural Science Foundation of China(Nos.22101135 and 21502096);the Natural Science Foundation of Jiangsu Province(No.BK20150652);the Fundamental Research Funds for the Central Universities(Nos.KYQN2022058,KJQN201629 and XUEKEN2022032);“333 High-Level Talent Project”of Jiangsu Province.
A dehydroxylative ring-opening Giese reaction of cyclobutanone oximes enabled by photoredox/Ti dual catalysis has been reported in this work.This protocol avoids the prefunctionalization of oximes and the use of stoic...
Project supported by the National Natural Science Foundation of China(Nos.92156008,22161142016);the Taishan Scholar Program at Shandong Province;the Natural Science Foundation of Shandong Province(No.ZR2020QB018)。
Manganese-catalyzed C—C bond cleavage of cyclobutanols has attracted great attention due to the high abundance and cheap and eco-friendly behaviour.A manganese-catalyzed ring-opening C—C bond fluorination of cyclobu...
support from the University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province(No.UNPYSCT-2017124)。
We report the unprecedent Pd(I)catalyzed ring-opening arylation of cyclopropyl-α-aminoamides.This protocol allows facile access to biologically important α-ketoamide-containing oligopeptides and even more challengin...
supported by the National Natural Science Foundation of China(No.52173093);Peking University Ge Li and Ning Zhao Life Science Research Fund for Young Scientists。
Poly(3-hydroxybutyrate),a crucial member of the large biodegradable polyhydroxyalkanoate family,suffers from its brittleness.To enhance its performance,we employed a straightforward approach involving the ring-opening...
the China Postdoc Council(OCPC)for the financial support of Postdoctoral International Exchange Program(No.YJ20210095);the financial support from the National Natural Science Foundation of China(No.22078150);National Key R&D Program of China(No.2021YFC2101904);the Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD),the Jiangsu Synergetic Innovation Center for Advanced Bio-Manufacture(No.XTB2201);the Top-Notch Academic Programs Project of Jiangsu Higher Education Institutions(TAPP)。
The innovation in polymer design to rival conventional polyethylene glycol(PEG)is an important approach to achieving a more sustainable society.Here,cyclic PEG-like polycarbonates having high molecular weight(4.4–49....
This work was financially supported by the National Natural Science Foundation of China(Nos.21861007 and 21702034);Natural Science Foundation of Guangxi Province(Nos.2021GXNSFAA075024 and 2022GXNSFAA035468);the Guangdong Basic and Applied Basic Research Foundation(No.2020A1515010624);Natural Science Foundation of Jiangxi Province of China(No.20212BAB213024);“BAGUI Scholar”Program of Guangxi Province of China.
A novel defluorinative ring-opening of gem-difluorocyclopropenes is presented,providing a concise and efficient method for accessing 2-fluoropropenals and 2-fluorobuta-1,3-dienes in moderate to good yields with excell...
the National Key R&D Program of China(No.2022YFA1504601);Startup Program of the State Key Laboratory for Oxo Synthesis and Selective Oxidation of LICP,China(No.E0SX0184);the National Natural Science Foundation of China(Nos.22102193,21972151);the Key Research Program of Frontier Science of CAS(No.QYZDJSSW-SLH051).
Selective activation of C-O bond is of fundamental importance in the precise conversion of oxygenates into value-added compounds in an atom-economic and sustainable manner, and meanwhile, the structurally well-defined...