Copper-Catalyzed Ring-Opening Hydrosilylation and Hydroboration of Arylidenecyclopropanes  

作　　者：Zhen-Yu Xiao Zi-Lu Wang Yun-He Xu 

机构地区：[1]Department of Chemistry,University of Science and Technology of China,96 Jinzhai Road,Hefei,Anhui 230026,China

出　　处：《Chinese Journal of Chemistry》2025年第4期385-392,共8页中国化学(英文版)

基　　金：the funding of the National Natural Science Foundation of China(22371269);the State Key Laboratory of Elementoorganic Chemistry Nankai University(202001);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0450301);the Open Project of Key Laboratory of Organosilicon Chemistry,and Material Technology of Ministry of Education,Hangzhou Normal University(KFJJ2022013);Anhui Provincial Major Science and Technology Project(2022e03020005).

摘　　要：Arylidenecyclopropanes(ACPs)are highly strained substrates that can be readily utilized for diverse transformations.This study showcases the outcomes of copper-catalyzed ring-opening hydrosilylation and hydroboration reactions of ACPs,showcasing precise cleavage of C—C bonds.The reaction presents an effective and convenient method for producing homoallylic silanes and boronates.

关 键 词：HYDROSILYLATION HYDROBORATION Copper catalysis Arylidenecyclopropanes 

分 类 号：O62[理学—有机化学]