the funding of the National Natural Science Foundation of China(22371269);the State Key Laboratory of Elementoorganic Chemistry Nankai University(202001);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0450301);the Open Project of Key Laboratory of Organosilicon Chemistry,and Material Technology of Ministry of Education,Hangzhou Normal University(KFJJ2022013);Anhui Provincial Major Science and Technology Project(2022e03020005).
Arylidenecyclopropanes(ACPs)are highly strained substrates that can be readily utilized for diverse transformations.This study showcases the outcomes of copper-catalyzed ring-opening hydrosilylation and hydroboration ...
Carbon dioxide(CO_(2))serves as a sustainable carbon source for building biomass,fossil fuels,and organic chemicals.Converting CO_(2) into value-added chemicals or fuels is an ideal approach to achieve carbon cycling....
the National Key R&D Program of China(grant no.2021YFF0701600);the National Natural Science Foundation of China(grant no.22225103);Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs,Shanghai Jiao Tong University,and the China Postdoctoral Science Foundation(grant nos.2020M680021 and 2021T140366),which was greatly appreciated.
Selective reduction of readily available N-heteroarenes is important in both organic synthesis and chemical biology.Herein,we describe ligand-controlled regiodivergent hydroboration of quinolines using well-defined am...
Financial support from National Natural Science Foundation of China (22171260);K.C.Wong Education Foundation of CAS (GJTD-2020-08)is acknowledged.
The planar-chiral ligands have been widely applied as a class of unique and significant ligands in asymmetric catalysis.Among them,chiral[2.2]paracycyclophane has emerged as a privileged type of planar-chiral framewor...
supported by the National Natural Science Foundation of China(Grant Nos.21871107,22225104,21975102,22071077).
It is very important to develop efficient synthetic strategies for site-specific functionalization of tetrahydroquinolines due to their indispensable roles in pharmaceutical and agrochemical industries.We apply hard/s...
the financial support from the National Natural Science Foundation of China (Nos. 22022102 and 22071010);the financial support from China Postdoctoral Science Foundation (No. 2021M700462)。
We report two air-stable nickel(II) half-sandwich complexes,Cp*Ni(1,2-Cy_(2)PC_(6)H_(4)O)(1) and Cp*Ni(1,2-Ph_(2)PC_(6)H4NH)(2),for cooperative B-H bond activation and their applications in catalytic hydroboration of ...
The authors acknowledge financial support from the National Natural Science Foundation of China(No.21821002).
The sustainable development of synthetic reactions catalyzed by earth-abundant metals is one of the principal goals in homogeneous catalysis.However,so far most of the protocols are still plagued by sophisticated liga...
supported by the National Natural Science Foundation of China(Grant No.91961116);the Fundamental Research Funds for the Central Universities,and Programs for high-level entrepreneurial and innovative talents introduction of Jiangsu Province。
The strong oxophilicity of actinide complexes prevents their applications in the transformation of oxygen-containing substrates.Herein,we report the use of a uranium(Ⅳ)alkyl complex as a catalyst for the hydroboratio...
Developing mild and efficient catalytic methods for the selective synthesis of amines is a longstanding research objective.In this respect,catalytic deoxygenative amide reduction has proven to be promising but challen...
the financial support from the National Natural Science Foundation of China(Nos.21871269 and 21521002).
Main observation and conclusion In this work,a novel mode for the activation of N-heterocyclic carbene boranes(NHC-boranes)was developed by generating the highly reactive zwitterion species through hydride abstraction...