A Uranium(Ⅳ) Alkyl Complex: Synthesis and Catalytic Property in Carbonyl Hydroboration  

作　　者：Xiong Sun Xingxing Gong Zhuoyi Xie Congqing Zhu 

机构地区：[1]State Key Laboratory of Coordination Chemistry,Jiangsu Key Laboratory of Advanced Organic Materials,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing,Jiangsu,210093 China

出　　处：《Chinese Journal of Chemistry》2022年第17期2047-2053,共7页中国化学（英文版）

基　　金：supported by the National Natural Science Foundation of China(Grant No.91961116);the Fundamental Research Funds for the Central Universities,and Programs for high-level entrepreneurial and innovative talents introduction of Jiangsu Province。

摘　　要：The strong oxophilicity of actinide complexes prevents their applications in the transformation of oxygen-containing substrates.Herein,we report the use of a uranium(Ⅳ)alkyl complex as a catalyst for the hydroboration of carbonyl compounds.This reaction has good functional group tolerance and chemo-selectivity under mild conditions.This study represents the rare example of catalytic reaction promoted by a uranium alkyl complex and highlights the potential of uranium complexes in synthetic chemistry.

关 键 词：ACTINIDES HYDROBORATION URANIUM Uraniumcatalyst Triamidoamines 

分 类 号：O641.4[理学—物理化学]