BORANES

作品数：15被引量：3H指数：1
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相关领域：理学更多>>
相关作者：金成树刘涛更多>>
相关机构：上海工程技术大学绥化学院更多>>
相关期刊：《Science China Chemistry》《Chemical Research in Chinese Universities》《Chinese Journal of Chemistry》《贵金属》更多>>
相关基金：国家自然科学基金天津市自然科学基金更多>>
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Facile synthesis of the dodecahydridododecaborate(B_(12)H_(12)^(2-)) from borane Lewis base adducts
《Science China Chemistry》2025年第4期1355-1361,共7页Yi Jing Xin-Ran Liu Xinghua Wang Hui Han Sha-Sha Liang Xi-Meng Chen Donghui Wei Lai-Sheng Wang Xuenian Chen 
supported by the National Natural Science Foundation of China(22171246,U1804253 to X.Chen,and 21773214 to D.Wei);L.S.Wang wishes to thank the US National Science Foundation for support under grant CHE-2403841.
Polyhedral boranes are a class of well-known boron molecular clusters widely used in energy;chemistry;medicine;and materials science because of their unique physical and chemical properties.Great efforts have been mad...
关键词：dodecahydridododecaborates BORANES polyhedral boranes borane Lewis base adducts B-H bond condensation reactions 
Recent Advances in Methodologies for Radical-Mechanistic Borylation
《Chinese Journal of Chemistry》2025年第1期104-115,共12页Chang Lian Jianning Zhang Di Qiu Fanyang Mo 
National Natural Science Foundation of China(Grant Nos.22071004,21933001 and 22150013)for financial support.
We reviewed works on radical borylation reactions since 2020 from two aspects.1.Borylation from alkyl or aryl radicals:This approach involves the generation of alkyl or aryl radicals from various precursors such as ha...
关键词：Radical reactions Radicalmechanisms Organic methodologies Green chemistry BORANES 
Functionalization of Boranes through Thiol/Oxygen Catalysis
《Chinese Journal of Chemistry》2024年第22期2804-2810,共7页Hongyi Tao Hairong Lyu 
supported by research start-up fund(Project No.4933621)from the Chinese University of Hong Kong.Mr.Weixuan Sun is thanked for checking the experimental procedure。
A greener and more convenient alternative to traditional methods for the generation of thiyl radical as hydrogen atom transfer(HAT)catalyst is developed,using molecular oxygen to oxidize thiol without the need for che...
关键词：BORANES Thiyl radical Oxygen Borane difunctionalization Synthetic methods Green chemistry 
Superatom-assembled boranes,carboranes,and low-dimensional boron nanomaterials based on aromatic icosahedral B_(12)and C_(2)B_(10)
《Nano Research》2024年第7期6734-6740,共7页Qiao-Qiao Yan Yan-Fang Wei Qiang Chen Yue-Wen Mu Si-Dian Li 
supported by the National Natural Science Foundation of China(Nos.22373061,21973057,and 22003034).
Using the experimentally known aromatic icosahedral superatoms I_(h)B_(12)H_(12)2−and D_(5d)1,12-C_(2)B_(10)H_(12)as building blocks and based on extensive density functional theory calculations,we predict herein a se...
关键词：superatom-assembling bottom-up approach density functional theory superpolyhedral boranes superpolyhedral carboranes borophanes 
Asymmetric Partial Hydrosilylation of 2,2-Difluoro-1,3-diketones with Chiral Frustrated Lewis Pairs
《Chinese Journal of Chemistry》2024年第8期853-857,共5页Ting Liu Xiangqing Feng Haifeng Du 
the financial support from the National Natural Science Foundation of China(21825108 and 22331011).
Comprehensive Summary,The asymmetric partial reduction of 1,3-diketones stands as a straightforward pathway to access optically active β-hydroxyketones. In this paper, an asymmetric Piers-type hydrosilylation of 2,2-...
关键词：Asymmetric catalysis HYDROSILYLATION Ketones Frustrated Lewis pairs Chiral boranes 
Asymmetric Hydrogenation of Phenanthridines with Chiral Boranes
《Chinese Journal of Chemistry》2024年第6期631-635,共5页Guangyu Cui Xiangqing Feng Haifeng Du 
financial support from the National Natural Science Foundation of China(21825108 and 22331011).
The asymmetric hydrogenation of N-heteroarenes provides an efficient method for the synthesis of optically active cyclic secondary amines.In this paper,we described an asymmetric hydrogenation of phenanthridines using...
关键词：Asymmetric catalysis HYDROGENATION Nitrogen heterocycles PHENANTHRIDINES Frustrated Lewis pairs Chiral boranes 
Selective synthesis of the B_(11)H_(14)^(-) and B_(12)H_(12)^(2-) borane derivatives and the general mechanisms of the B-H bond condensation
《Science China Chemistry》2024年第3期876-881,共6页Yi Jing Xinghua Wang Hui Han Xin-Ran Liu Xing-Chao Yu Xi-Meng Chen Donghui Wei Lai-Sheng Wang Xuenian Chen 
supported by the National Natural Science Foundation of China(22171246,U1804253 to X.C.and 21773214 to D.W.);the National Science Foundation(CHE-2053541 to L.-S.W.)。
Polyhedral boranes are a class of well-known boron molecular clusters with unique physical and chemical properties,and great efforts have been made in the past decades to find more effective synthetic methods.However,...
关键词：BORANES polyhedral boranes dihydrogen bond NUCLEOPHILICITY 
Visible Light-Induced C-5 Selective C-H Radical Borylation of Imidazo[1,2-a]pyridines with NHC-Boranes被引量：1
《Chinese Journal of Chemistry》2023年第2期193-198,共6页Huitao Zheng Hao Lu Chaobo Su Runlong Yang Limin Zhao Xiang Liu Hua Cao 
This work was supported by the Innovation and Strong School Project of Guangdong Pharmaceutical University(2021ZDzX2028);the Scientific and Technological Innovation Leading Talent Project of Zhongshan City(LJ2021009);a Start-up Grant from Guangdong Pharmaceutical University(Grant Nos.51361303,51361304).
A visible-light-induced C-5 selective C-H borylation of imidazo[1,2-a]pyridines with NHC-BH3 via Minisci-type radical borylation re-action has been developed for the first time.The present sustainable protocol provide...
关键词：PHOTOCHEMISTRY Boron C-H activation Imidazo[12-a]pyridines RADICALS Synthetic methods 
Dehydrocoupling of boranes with amines using a scandium catalyst
《Chinese Chemical Letters》2021年第12期4002-4005,共4页Yang Wang Pengfei Xu Xin Xu 
supported by the National Natural Science Foundation of China (No. 21871204)。
The scandocene alkyl complex(C_(5)Me_(5))_(2)ScCH_(2)SiMe_(3)was found to be an efficient catalyst for the dehydrocoupling of the non-cyclic boranes, dicyclohexylborane and thexylborane, with amines under mild conditi...
关键词：BORANE Aminoborane DEHYDROCOUPLING SCANDIUM β-H elimination 
Divergent Synthesis of N-Heterocycles by Merging Borane- Mediated Cyclopropane Ring-Opening and Hydride Abstraction
《Chinese Journal of Chemistry》2021年第6期1641-1645,共5页Zi-Yu Zhang Jie Ren Ming Zhang Xiu-Fang Xu Xiao-Chen Wang 
the National Natural Science Foundation of China(Nos.21871147 and 91956106);the Natural Science Foundation of Tianjin(Nos.20JCZDJC00720 and 20JGQJC00030);the NCC Fund(No.NCC2020PY10);the Fundamental Research Funds for Central Universities(No.2122018165).X.-C.W.thanks the Tencent Foundation for support via the Xplorer Prize.This paper is dedicated to the 100th anniversary of the chemistry department at Nankai University.
Herein,we report the synthesis of N-heterocycles by borane-catalyzed dehydrogenative cyclization of 2-cyclopropyl-N,N-dimethyl-anilines.Borane-mediated cyclopropane ring-opening and borane-mediated hydride abstraction...
关键词：BORANES Lewis acids Cyclization HETEROCYCLES Hydrides 
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