Recent Advances in Methodologies for Radical-Mechanistic Borylation  

作　　者：Chang Lian Jianning Zhang Di Qiu Fanyang Mo 

机构地区：[1]College of Engineering,Peking University,Beijing,100871 China [2]School of Materials Science and Engineering,Peking University,Beijing,100871 China [3]Tianjin Key Laboratory of Structure and Performance for Functional Molecules,College of Chemistry,Tianjin Normal University,Tianjin,300387 China

出　　处：《Chinese Journal of Chemistry》2025年第1期104-115,共12页中国化学(英文版)

基　　金：National Natural Science Foundation of China(Grant Nos.22071004,21933001 and 22150013)for financial support.

摘　　要：We reviewed works on radical borylation reactions since 2020 from two aspects.1.Borylation from alkyl or aryl radicals:This approach involves the generation of alkyl or aryl radicals from various precursors such as halides and carboxylic acids,followed by their reaction with diboron reagents to form boron esters.2.Borylation from boron-centered radicals:This approach involves generating boron-centered radicals,which then react with substrates to achieve borylation.

关 键 词：Radical reactions Radicalmechanisms Organic methodologies Green chemistry BORANES 

分 类 号：O62[理学—有机化学]