Functionalization of Boranes through Thiol/Oxygen Catalysis  

作　　者：Hongyi Tao Hairong Lyu 

机构地区：[1]Departmentof Chemistry,The Chinese University of Hong Kong,Shatin,N.T.,Hong Kong SAR,China

出　　处：《Chinese Journal of Chemistry》2024年第22期2804-2810,共7页中国化学（英文版）

基　　金：supported by research start-up fund(Project No.4933621)from the Chinese University of Hong Kong.Mr.Weixuan Sun is thanked for checking the experimental procedure。

摘　　要：A greener and more convenient alternative to traditional methods for the generation of thiyl radical as hydrogen atom transfer(HAT)catalyst is developed,using molecular oxygen to oxidize thiol without the need for chemical initiators or light irradiation.The thiol/oxygen catalysis enables selective and efficient difunctionalization of borane.

关 键 词：BORANES Thiyl radical Oxygen Borane difunctionalization Synthetic methods Green chemistry 

分 类 号：O64[理学—物理化学]