HYDROSILYLATION

作品数:93被引量:103H指数:5
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相关领域:理学更多>>
相关作者:周红卫周辉李晓燕孙宏建彭啸更多>>
相关机构:大连理工大学山东大学桂林理工大学北京化工大学更多>>
相关期刊:《Chinese Journal of Polymer Science》《Journal of Surface Engineered Materials and Advanced Technology》《Wuhan University Journal of Natural Sciences》《Chinese Physics B》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划上海市教育委员会重点学科基金中国博士后科学基金更多>>
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Copper-Catalyzed Ring-Opening Hydrosilylation and Hydroboration of Arylidenecyclopropanes
《Chinese Journal of Chemistry》2025年第4期385-392,共8页Zhen-Yu Xiao Zi-Lu Wang Yun-He Xu 
the funding of the National Natural Science Foundation of China(22371269);the State Key Laboratory of Elementoorganic Chemistry Nankai University(202001);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0450301);the Open Project of Key Laboratory of Organosilicon Chemistry,and Material Technology of Ministry of Education,Hangzhou Normal University(KFJJ2022013);Anhui Provincial Major Science and Technology Project(2022e03020005).
Arylidenecyclopropanes(ACPs)are highly strained substrates that can be readily utilized for diverse transformations.This study showcases the outcomes of copper-catalyzed ring-opening hydrosilylation and hydroboration ...
关键词:HYDROSILYLATION HYDROBORATION Copper catalysis Arylidenecyclopropanes 
Iron-Catalyzed Selective Hydrogenation and Hydroboration/Hydrosilylation of CO_(2)
《有机化学》2024年第10期3106-3116,共11页Zhao Qiuting Wang Wenguang 
Carbon dioxide(CO_(2))serves as a sustainable carbon source for building biomass,fossil fuels,and organic chemicals.Converting CO_(2) into value-added chemicals or fuels is an ideal approach to achieve carbon cycling....
关键词:CO_(2)reduction HYDROGENATION hydroboration/hydrosilylation iron catalyst SELECTIVITY 
Rhodium(Ⅲ)-catalyzed diastereo-and enantioselective hydrosilylation/cyclization reaction of cyclohexadienone-tetheredα,β-unsaturated aldehydes
《Chinese Chemical Letters》2024年第9期160-164,共5页Yi-Fan Wang Hao-Yun Yu Hao Xu Ya-Jie Wang Xiaodi Yang Yu-Hui Wang Ping Tian Guo-Qiang Lin 
financial support from the National Key R&D Program of China(No.2022YFF1202600);the National Natural Science Foundation of China(Nos.22001172,22071155,and22371188);the Science and Technology Commission of Shanghai Municipality(Nos.20XD1403600 and 20400750300);the Shanghai Municipal Education Commission(No.2019-01-07-00-10-E00072);the Innovation Team and Talents Cultivation Program of National Administration of Traditional Chinese Medicine(No.ZYYCXTD-202004);the Shanghai Municipal Health Commission/Shanghai Municipal Administration of Traditional Chinese Medicine[No.ZY(2021-2023)-0501];Organizational Key R&D Program of SHUTCM(No.2023YZZ01)。
A rhodium(Ⅲ)-catalyzed hydrosilylation/cyclization reaction of cyclohexadienone-tetheredα,β-unsaturated aldehydes(1,6-dienes)with triethylsilane is described,providing a series of cishydrobenzofurans,cis-hydroindol...
关键词:Rhodium(Ⅲ)catalysis Hydrosilylation/cyclization 1 6-Dienes Silyl enol ether Diastereo-and enantioselectivity 
Heterometallic Mg-Ni-Mg Complex Promoted Hydrosilylation of Alkenes: Catalytic Performance and Intermediates Characterization
《Chinese Journal of Chemistry》2024年第18期2133-2139,共7页Yanping Cai Shengjie Jiang Xin Xu 
supported by the National Natural Science Foundation of China(22371198);the Postdoctoral Fellowship Programof CPSF(GZC20231885).
Background and Originality Content The catalytic hydrosilylation of unsaturated hydrocarbons,facilitated by transition metal(TM),is widely recognized as a proficient technique for the synthesis of high-value organosil...
关键词:Heterometallic complex Cooperative effect HYDROSILYLATION Magnesium Nickel hydride 
Co/Fe Dual Catalysis for Sequential Hydrosilylation-Isomerization:Access to Trisubstituted(E)-Alkenyl Silanes from Terminal Alkynes
《Chinese Journal of Chemistry》2024年第16期1860-1866,共7页Zhihao Guo Guixia Liu Zheng Huang 
the National Key R&D Program of China(2021YFA1500100);the National Natural Science Foundation of China(21825109,21821002,22072178,22293013);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0610000);CAS Project for Young Scientists in Basic Research(YSBR-094);Science and Technology Commission of Shanghai Municipality(23JC1404400);CAS Youth Interdisciplinary Team(JCTD-2021-11).
By rational modification of electronic and steric properties of pincer ligands,a Co/Fe dual catalyst system is developed for one-pot sequential Markovnikov alkyne hydrosilylation and stereoselective alkene isomerizati...
关键词:Cobalt Dual catalysis HYDROSILYLATION Iron ISOMERIZATION Trisubstituted alkenyl silanes 
Precise immobilization of metal single atoms into a porphyrinic metal-organic framework for an efficient alkene hydrosilylation
《Nano Research》2024年第7期5914-5921,共8页Chun-Ying Chen Qi-Jie Mo Fu-Zhen Li Hai-Li Song Li Zhang 
the National Natural Science Foundation of China(Nos.22371306 and 21821003);Guangdong Basic and Applied Basic Research Foundation(No.2019B151502017).
Alkene hydrosilylation is one of the most concise and atom-economical methods to synthesize organosilicon molecules.Herein,we reported the precise immobilization of metal single atoms(M-SAs;M=Ru,Rh,Ir,Pd,Pt,and Au)int...
关键词:alkene hydrosilylation single atom catalysts metal-organic frameworks precision chemistry synergistic catalysis 
Recent advances in heterogeneous hydrosilylation of unsaturated carbon-carbon bonds
《Chinese Chemical Letters》2024年第6期71-85,共15页Heng Yang Zhijie Zhou Conghui Tang Feng Chen 
the financial support from the National Natural Science Foundation of China(No.22001227);the Natural Science Foundation of Jiangsu Province(No.BK20200919);the“Jiangsu Specially-Appointed Professor Plan”;the Priority Academic Program Development of Jiangsu Higher Education Institutions。
The hydrosilylation of unsaturated carbon-carbon bonds is one of the most critical reactions in silicone industrial production.The homogeneous Speier's catalyst,Karstedt's catalyst,and other noble metal-based catalyst...
关键词:HYDROSILYLATION Heterogeneous catalysis ALKENES ALKYNES SILANES 
Asymmetric Partial Hydrosilylation of 2,2-Difluoro-1,3-diketones with Chiral Frustrated Lewis Pairs
《Chinese Journal of Chemistry》2024年第8期853-857,共5页Ting Liu Xiangqing Feng Haifeng Du 
the financial support from the National Natural Science Foundation of China(21825108 and 22331011).
Comprehensive Summary,The asymmetric partial reduction of 1,3-diketones stands as a straightforward pathway to access optically active β-hydroxyketones. In this paper, an asymmetric Piers-type hydrosilylation of 2,2-...
关键词:Asymmetric catalysis HYDROSILYLATION Ketones Frustrated Lewis pairs Chiral boranes 
Spin effect on redox acceleration and regioselectivity in Fe-catalyzed alkyne hydrosilylation被引量:1
《National Science Review》2024年第2期150-162,共13页Peng He Meng-Yang Hu Jin-Hong Li Tian-Zhang Qiao Yi-Lin Lu Shou-Fei Zhu 
supported by the National Key R&D Program of China (2021YFA1500200);National Natural Science Foundation of China (22001129, 92256301, 92156006, 21971119 and 22221002);Program of Introducing Talents of Discipline to Universities (‘111’ project, B06005) of the Ministry of Education of China;Haihe Laboratory of Sustainable Chemical Transformations;Fundamental Research Funds for the Central Universities;New Cornerstone Science Foundation through XPLORER PRIZE
Iron catalysts are ideal transition metal catalysts because of the Earths abundant,cheap,biocompatible features of iron salts.Iron catalysts often have unique open-shell structures that easily undergo spin crossover i...
关键词:spin effect spin-delocalization spin crossover iron-catalysis alkyne hydrosilylation 
Nickel-Catalyzed Regioselective Hydrosilylation of Conjugated Dienes
《Chinese Journal of Chemistry》2024年第1期13-19,I0004,共8页Xiaoyu Wu Wei Liu Liqun Yang Yue Wang Tianwen Liu Yao Yuan Yan Lu Zhaoguo Zhang 
With the increasing demand for homoallylic silanes and allylic silanes,the highly efficient and regioselective hydrosilylations of conjugated dienes are urgently needed.Herein,we developed a Ni-catalyzed regiodivergen...
关键词:NICKEL-CATALYZED Regioselective hydrosilylation Conjugated dienes Electrophilic activation Homoallylic silanes 
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