相关期刊:《Chinese Journal of Polymer Science》《Journal of Surface Engineered Materials and Advanced Technology》《Wuhan University Journal of Natural Sciences》《Chinese Physics B》更多>>
the funding of the National Natural Science Foundation of China(22371269);the State Key Laboratory of Elementoorganic Chemistry Nankai University(202001);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0450301);the Open Project of Key Laboratory of Organosilicon Chemistry,and Material Technology of Ministry of Education,Hangzhou Normal University(KFJJ2022013);Anhui Provincial Major Science and Technology Project(2022e03020005).
Arylidenecyclopropanes(ACPs)are highly strained substrates that can be readily utilized for diverse transformations.This study showcases the outcomes of copper-catalyzed ring-opening hydrosilylation and hydroboration ...
Carbon dioxide(CO_(2))serves as a sustainable carbon source for building biomass,fossil fuels,and organic chemicals.Converting CO_(2) into value-added chemicals or fuels is an ideal approach to achieve carbon cycling....
financial support from the National Key R&D Program of China(No.2022YFF1202600);the National Natural Science Foundation of China(Nos.22001172,22071155,and22371188);the Science and Technology Commission of Shanghai Municipality(Nos.20XD1403600 and 20400750300);the Shanghai Municipal Education Commission(No.2019-01-07-00-10-E00072);the Innovation Team and Talents Cultivation Program of National Administration of Traditional Chinese Medicine(No.ZYYCXTD-202004);the Shanghai Municipal Health Commission/Shanghai Municipal Administration of Traditional Chinese Medicine[No.ZY(2021-2023)-0501];Organizational Key R&D Program of SHUTCM(No.2023YZZ01)。
A rhodium(Ⅲ)-catalyzed hydrosilylation/cyclization reaction of cyclohexadienone-tetheredα,β-unsaturated aldehydes(1,6-dienes)with triethylsilane is described,providing a series of cishydrobenzofurans,cis-hydroindol...
supported by the National Natural Science Foundation of China(22371198);the Postdoctoral Fellowship Programof CPSF(GZC20231885).
Background and Originality Content The catalytic hydrosilylation of unsaturated hydrocarbons,facilitated by transition metal(TM),is widely recognized as a proficient technique for the synthesis of high-value organosil...
the National Key R&D Program of China(2021YFA1500100);the National Natural Science Foundation of China(21825109,21821002,22072178,22293013);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0610000);CAS Project for Young Scientists in Basic Research(YSBR-094);Science and Technology Commission of Shanghai Municipality(23JC1404400);CAS Youth Interdisciplinary Team(JCTD-2021-11).
By rational modification of electronic and steric properties of pincer ligands,a Co/Fe dual catalyst system is developed for one-pot sequential Markovnikov alkyne hydrosilylation and stereoselective alkene isomerizati...
the National Natural Science Foundation of China(Nos.22371306 and 21821003);Guangdong Basic and Applied Basic Research Foundation(No.2019B151502017).
Alkene hydrosilylation is one of the most concise and atom-economical methods to synthesize organosilicon molecules.Herein,we reported the precise immobilization of metal single atoms(M-SAs;M=Ru,Rh,Ir,Pd,Pt,and Au)int...
the financial support from the National Natural Science Foundation of China(No.22001227);the Natural Science Foundation of Jiangsu Province(No.BK20200919);the“Jiangsu Specially-Appointed Professor Plan”;the Priority Academic Program Development of Jiangsu Higher Education Institutions。
The hydrosilylation of unsaturated carbon-carbon bonds is one of the most critical reactions in silicone industrial production.The homogeneous Speier's catalyst,Karstedt's catalyst,and other noble metal-based catalyst...
the financial support from the National Natural Science Foundation of China(21825108 and 22331011).
Comprehensive Summary,The asymmetric partial reduction of 1,3-diketones stands as a straightforward pathway to access optically active β-hydroxyketones. In this paper, an asymmetric Piers-type hydrosilylation of 2,2-...
supported by the National Key R&D Program of China (2021YFA1500200);National Natural Science Foundation of China (22001129, 92256301, 92156006, 21971119 and 22221002);Program of Introducing Talents of Discipline to Universities (‘111’ project, B06005) of the Ministry of Education of China;Haihe Laboratory of Sustainable Chemical Transformations;Fundamental Research Funds for the Central Universities;New Cornerstone Science Foundation through XPLORER PRIZE
Iron catalysts are ideal transition metal catalysts because of the Earths abundant,cheap,biocompatible features of iron salts.Iron catalysts often have unique open-shell structures that easily undergo spin crossover i...
With the increasing demand for homoallylic silanes and allylic silanes,the highly efficient and regioselective hydrosilylations of conjugated dienes are urgently needed.Herein,we developed a Ni-catalyzed regiodivergen...