Recent advances in heterogeneous hydrosilylation of unsaturated carbon-carbon bonds  

作　　者：Heng Yang Zhijie Zhou Conghui Tang Feng Chen 

机构地区：[1]School of Chemistry and Chemical Engineering,Yangzhou University,Yangzhou 225002,China [2]Key Laboratory of Material Chemistry for Energy Conversion and Storage,Ministry of Education,Hubei Key Laboratory of Material Chemistry and Service Failure,School of Chemistry and Chemical Engineering,Huazhong University of Science and Technology,Wuhan 430074,China

出　　处：《Chinese Chemical Letters》2024年第6期71-85,共15页中国化学快报（英文版）

基　　金：the financial support from the National Natural Science Foundation of China(No.22001227);the Natural Science Foundation of Jiangsu Province(No.BK20200919);the“Jiangsu Specially-Appointed Professor Plan”;the Priority Academic Program Development of Jiangsu Higher Education Institutions。

摘　　要：The hydrosilylation of unsaturated carbon-carbon bonds is one of the most critical reactions in silicone industrial production.The homogeneous Speier's catalyst,Karstedt's catalyst,and other noble metal-based catalysts are widely used.However,simplifying the separation of the homogeneous catalyst from reaction products and reducing the high cost of precious metals is still challenging.This review describes the recent development of heterogeneous catalysts for alkene,alkyne,and allene hydrosilylations,which can effectively solve problems in homogeneous hydrosilylation.

关 键 词：HYDROSILYLATION Heterogeneous catalysis ALKENES ALKYNES SILANES 

分 类 号：O627.41[理学—有机化学] O643.36[理学—化学]