BORANE

作品数：39被引量：36H指数：4
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相关领域：理学更多>>
相关作者：戴伟民更多>>
相关机构：中国海洋大学香港科技大学更多>>
相关期刊：《合成化学》《Science Bulletin》《Chinese Journal of Catalysis》《Chinese Journal of Chemistry》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划湖北省自然科学基金国家教育部博士点基金更多>>
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Enhanced Efficiency of Amide-Substituted Quinuclidine-Boranes as Hydridic Hydrogen Atom Transfer Catalysts for Photoinduced Hydroalkylation of Unactivated Olefins
《Chinese Journal of Chemistry》2024年第24期3227-3233,共7页Xiao Yang Mengdi Ma Meichen Xu Yubing Pang Haiying Zhao Juntao Ye 
the National Natural Science Foundation of China(grant nos.22371180 and 22001163 to Y.J.and 22361032 to H.Z.);Shanghai Jiao Tong University(SJTU)is acknowledged.Dr.Pandaram Sakthivel(SJTU)is acknowledged for reproducing the results of compounds 6,10,and 21.
An amide-substituted quinuclidine-borane has been identified as a more efficient hydridic hydrogen atom transfer(HAT)catalyst for the hydroalkylation of unactivated olefins under visible-light irradiation.^(1)H NMR ti...
关键词：Hydrogen atom transfer BORANE Unactivated olefin HYDROALKYLATION Photocatalysis 
Functionalization of Boranes through Thiol/Oxygen Catalysis
《Chinese Journal of Chemistry》2024年第22期2804-2810,共7页Hongyi Tao Hairong Lyu 
supported by research start-up fund(Project No.4933621)from the Chinese University of Hong Kong.Mr.Weixuan Sun is thanked for checking the experimental procedure。
A greener and more convenient alternative to traditional methods for the generation of thiyl radical as hydrogen atom transfer(HAT)catalyst is developed,using molecular oxygen to oxidize thiol without the need for che...
关键词：BORANES Thiyl radical Oxygen Borane difunctionalization Synthetic methods Green chemistry 
Selective synthesis of the B_(11)H_(14)^(-) and B_(12)H_(12)^(2-) borane derivatives and the general mechanisms of the B-H bond condensation
《Science China Chemistry》2024年第3期876-881,共6页Yi Jing Xinghua Wang Hui Han Xin-Ran Liu Xing-Chao Yu Xi-Meng Chen Donghui Wei Lai-Sheng Wang Xuenian Chen 
supported by the National Natural Science Foundation of China(22171246,U1804253 to X.C.and 21773214 to D.W.);the National Science Foundation(CHE-2053541 to L.-S.W.)。
Polyhedral boranes are a class of well-known boron molecular clusters with unique physical and chemical properties,and great efforts have been made in the past decades to find more effective synthetic methods.However,...
关键词：BORANES polyhedral boranes dihydrogen bond NUCLEOPHILICITY 
A metal-free coordination–insertion ring-opening polymerization of tetrahydrofuran by the central metalloid bis(pentafluorophenyl)(phenoxy)borane
《Chinese Chemical Letters》2024年第3期419-422,共4页Cheng Wu Yixuan Liu Chunsheng Xiao Chenyang Hu Xuan Pang Xuesi Chen 
funded by the National Key R&D Program of China(No.2021YFA1501700);the Science and Technology Development Plan of Jilin Province(Nos.20230101042JC,20210201059GX);the National Natural Science Foundation of China,Basic Science Center Program(No.51988102);the National Natural Science Foundation of China(Nos.52203017,52073272 and 22293062);Bureau of International Cooperation Chinese Academy of Sciences(No.029GJHZ2023017MI)。
A new strategy for the metal-free coordination–insertion ring-opening polymerization of tetrahydrofuran by the central metalloid Boron has been first identified.Bis(pentafluorophenyl)(phenoxy)borane was used as a cat...
关键词：Metal-free catalyst Bis(pentafluorophenyl)(phenoxy)borane Coordination–insertion mechanism Ring-opening polymerization Polytetrahydrofuran 
Iron/B_(2)pin_(2)catalytic system enables the generation of alkyl radicals from inert alkyl C-O bonds for amine synthesis
《Chinese Chemical Letters》2024年第1期227-232,共6页Yanqing Zhu Shuai Chen Zhen Zhou Yun He Zhengli Liu Yang Liu Zhang Feng 
the financial support from National Natural Science Foundation of China(Nos.22271031,22201026),Natural Science Foundation of Chongqing(No.CSTB2022NSCQ-MSX1065);Chongqing Postdoctoral Science Foundation(No.cstc2020jcyj-bshX0052);Medical Imaging Key Laboratory of Sichuan Province(Nos.MIKL202201 and MIKL202202);Affiliated Hospital of North Sichuan Medical College(No.2022JB001);Youth Project of Science and Technology Research Program of Chongqing Education Commission of China(No.KJQN201900112).
A method for the generation of alkyl radicals from inert alkyl C-o bonds has been developed via an iron/borane reagent/alkoxide catalytic system,which can be employed for the synthesis of amines from nitroarenes with ...
关键词：C-N bond formation Reductive amination Borane reagent Iron catalysis Green chemistry 
Y_(2)O_(3)-functionalized graphene-immobilized Ni–Pt nanoparticles for enhanced hydrous hydrazine and hydrazine borane dehydrogenation被引量：4
《Rare Metals》2023年第10期3410-3419,共10页Qi-Lu Yao Meng He Ya-Ru Kong Tian Gui Zhang-Hui Lu 
financially supported by the National Natural Science Foundation of China (Nos. 22162013 and 22162014);Natural Science Foundation of Jiangxi Province (No. 20212ACB204009);the Program of the Academic and Technical Leaders of Major Disciplines of Jiangxi Province (No. 20212BCJL23059);the Thousand Talents Plan of Jiangxi Province;the Open Project Program of State-Province Joint Engineering Laboratory of Zeolite Membrane Materials of China (No. SPJELZMM-202210)。
Developing efficient and highly selective catalyst to promote hydrogen generation from hydrous hydrazine(N_(2)H_(4)·H_(2)O) and hydrazine borane(N_(2)H_(4)BH_(3))remains a challenging issue for fuel cell-based hydrog...
关键词：Hydrous hydrazine(N_(2)H_(4)·H_(2)O) Hydrazine borane(N_(2)H_(4)BH_(3)) DEHYDROGENATION GRAPHENE Catalysis 
Facile Synthesis of Polycarbonate Diol via Copolymerization of CO_(2) and Cyclohexene Oxide Catalysed by a Combination of One-Component Phosphonium Borane Lewis Pair and Water被引量：2
《Chinese Journal of Polymer Science》2023年第5期735-744,I0009,共11页Xiao-Wu Wang Ji-Wen Hui Yu-Tao Li Yan-Ru Gu Zhi-Bo Li 
financially supported by the National Key R&D Program of China(No.2021YFA1501600);the National Natural Science Foundation of China(Nos.22175105 and 22031005)。
Well-defined polycarbonate diol was successfully synthesized through a strategy using a combination of organocatalyst and water.Such strategy was less developed in organocatalyzed polymerization and frequently regarde...
关键词：Polycarbonate Phosphonium borane Lewis pair CO_(2)utilization Organocatalysis Ring-opening polymerization 
Controlled synthesis of GeSe_(2) and GeSe nanostructures induced by TBAB被引量：1
《Rare Metals》2023年第1期189-197,共9页Huan Yang Yue Wu Li-Yan Hu Juan-Juan Wang Fang Wang Xiao-Hong Xu 
supported by the National Natural Science Foundation of China(Nos.51971122 and 12174237);Technological Innovation Programs of Higher Education Institutions in Shanxi(No.2021Y440)。
Ge-based selenides have attracted extensive attention as promising candidates for future optoelectronic applications.Despite great progress has been achieved,the controlled synthesis of GeSe2and GeSe nanostructures an...
关键词：GeSe_(2) GeSe Borane tert-butylamine complex(TBAB) Liquid-phase method BANDGAPS 
Boron-promoted reductive deoxygenation coupling reaction of sulfonyl chlorides for the C(sp3)-S bond construction被引量：1
《Chinese Chemical Letters》2022年第12期5101-5105,共5页Shuo Chen Qingru Wen Yanqing Zhu Yanru Ji Yu Pu Zhengli Liu Yun He Zhang Feng 
support from Natural Science Foundation of Sichuan(No.2021YJ0413);Sichuan Key Laboratory of Medical Imaging(North Sichuan Medical College,No.SKLMI201901);Strategic Cooperation of Science and Technology between Nanchong City and North Sichuan Medical College(Nos.19SXHZ0441,19SXHZ0227);Chongqing Postdoctoral Science Foundation(No.cstc2020jcyj-bshX0052);China Postdoctoral Science Foundation(No.2020M673121).
Herein,we report a borane-promoted reductive deoxygenation coupling reaction to synthesize sulfides.This reaction features excellent functional group compatibility,high efficiency,broad substrate scope,and application...
关键词：C-S bond formation Reductive deoxygenation coupling BORANE Organosulfur compounds Green chemistry 
Neurotoxicity due to dimethylamine borane poisoning via skin absorption:a case report
《World Journal of Emergency Medicine》2022年第6期500-503,共4页Guang-cai Yu Ya-qian Li Tian-zi Jian Bao-tian Kan Si-qi Cui Ping Han Xiang-dong Jian 
Scientific Research Project of Qilu Hospital,Shandong University(project no.KYLL-2019-296).
Dear editor,Dimethylamine borane(DMAB,CAS no.74-94-2),also called boron-dimethylamine complex,is a white crystalline solid.It has an amine odour under mild conditions.[1]As an excellent reducing agent,DMAB is widely u...
关键词：conditions. ABSORPTION BORON 
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