Dicyano-Functionalized MCM-41-Supported Palladium Complex as An Efficient Catalyst for Allylation of Aldehydes and Ketones  

作　　者：赵红 蔡明中 

机构地区：[1]Department of Chemistry, Jiangxi Normal University, Nanchang, Jiangxi 330027, China [2]Department of Pharmacy, Guangdong Pharmaceutical College, Guangzhou, Guangdong 510240, China

出　　处：《Chinese Journal of Chemistry》2006年第11期1669-1673,共5页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China （No. 20462002）.

摘　　要：Dicyano-functionalized MCM-41-supported palladium complex was prepared from dicyano-functionalized MCM-41 and palladium chloride. This complex exhibited high catalytic activity in the allylation of aldehydes and ketones with allylic chlorides in the presence of SnCl2. This polymeric palladium complex can be recovered and reused without noticeable loss of activity.Dicyano-functionalized MCM-41-supported palladium complex was prepared from dicyano-functionalized MCM-41 and palladium chloride. This complex exhibited high catalytic activity in the allylation of aldehydes and ketones with allylic chlorides in the presence of SnCl2. This polymeric palladium complex can be recovered and reused without noticeable loss of activity.

关 键 词：ALLYLATION dicyano-functionalized MCM-41 heterogeneous palladium catalysis homoallylic alcohol 

分 类 号：O623.42[理学—有机化学]