ALLYLATION

作品数:56被引量:27H指数:3
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相关领域:理学更多>>
相关作者:王晓霞石磊王喜存权正军更多>>
相关机构:大连理工大学西北师范大学郑州大学南京工业大学更多>>
相关期刊:《Journal of Donghua University(English Edition)》《有机化学》《Green Synthesis and Catalysis》《Organic Chemistry Frontiers》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金湖北省自然科学基金更多>>
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Photocatalytic Aldehyde Allylation for Site-Specific DNA Functionalization
《Chinese Journal of Chemistry》2025年第1期97-103,共7页Yixin Zhang Ying Huang Qiaoling Che Yiyun Chen 
Financial support was provided by the National Natural Science Foundation of China(22337005,22277133,91753126);Youth Innovation Promotion Association CAs(2023266);CAS Interdisciplinary Innovation Team(JCTD-2020-16);Program of Shanghai Academic/Technology Research Leader(21XD1424700);International Partnership Program of the Chinese Academy of Science(033GJHZ2023006FN).
Enhancing the DNA toolbox with innovative photochemical reactions is pivotal for advancing nucleic acid-based technologies.Aldehyde groups,versatile bioorthogonal handles for imine formation under acidic conditions,ar...
关键词:DNA functionalization Photocatalysis Site-specific modification Aldehyde Nucleic acids ALLYLATION DNA 
Asymmetric radical allylation of β-keto esters with vinyl cyclopropanes by dual photoredox/nickel catalysis被引量:1
《Science China Chemistry》2024年第11期3807-3816,共10页Wen-Yuan Qu Xue-Song Zhou Wen-Jing Xiao Jia-Rong Chen 
the National Natural Science Foundation of China (22171099, and 92256301);the National Key R&D Program of China (2023YFA1507203 and 2022YFA1506100);the Open Research Fund of School of Chemistry and Chemical Engineering;the Fundamental Research Funds for the Central Universities of China (CCNU24JCPT016);Henan Normal University (2021YB02);the Double-Thousand Talents Plan of Jiangxi Province (jxsq2023102004)。
Radical-involved allylation reactions have emerged as a powerful platform for construction of carbon-carbon and carbonheteroatom bonds, facilitating the strategic incorporation of diverse allyl moieties. Nevertheless,...
关键词:asymmetric allylation photoredox catalysis radical addition nickel catalysis β-keto esters vinyl cyclopropanes 
Pd/Zn Dual Catalysis for Site-,Enantio-,and Diastereo-Divergent 2-(Alkoxycarbonyl)allylation ofα-Hydroxyketones with Morita–Baylis–Hillman Adducts
《CCS Chemistry》2024年第10期2607-2618,共12页Yong Liu Chaopeng Li Rui Zhang Zibo Liu Zhaobin Han Zheng Wang Kuiling Ding 
the National Key R&D Program of China(grant nos.2023YFA1506700,2022YFA1503702,and 2021YFF0701602);National Natural Science Foundation of China(NSFC,grant nos.22231011 and 22271303);Shanghai Scientific and Technological Innovation Project,China(grant no.22JC1401000).
A synergistic Pd/Zn dual chiral catalyst system has been developed for the stereodivergent transformation of Morita–Baylis–Hillman(MBH)carbonates and unprotectedα-hydroxyketones to afford the corresponding allylati...
关键词:asymmetric catalysis Pd/Zn dual catalyst 2-(alkoxycarbonyl)allylation stereodivergent sitedivergent 
Ru(II)-Catalyzed ortho C-H Allylation of N-Aryl-7-azaindoles with 2-Methylidene Cyclic Carbonate被引量:1
《Chinese Journal of Chemistry》2024年第9期985-989,共5页Jing Zhang Quan-Jian Luo Han-Chi Wang Jin-Heng Li Bo Sun 
supported by the Natural Science Foundation of Shandong Province(ZR2019BB011);the Scientific Research Foundation of Qingdao University of Science&Technology(010029022).
A Ru(II)-catalyzed ortho allylation reaction of N-aryl-7-azaindole with readily available 2-methylidene cyclic carbonate has been developed.This reaction is an effective pathway for synthesizing 7-azaindole derivative...
关键词:Ru(II) ALLYLATION N-Aryl-7-azaindoles Cyclic carbonates Heterocyclic compounds C-H activation 
Palladium-Catalyzed Regioselective Asymmetric Chemodivergent Allylation of Oxazolones with Morita-Baylis-Hillman Adducts被引量:1
《CCS Chemistry》2023年第12期2790-2798,共9页Rui Zhang Zibo Liu Yong Liu Haoran Yang Xiaoming Wang Zhaobin Han Zheng Wang Kuiling Ding 
financial supports from the National Key R&D Program of China(grant nos.2022YFA1503702 and 2021YFF0701602);NSFC(grant nos.22231011 and 22271303).
Oxazolones are structural subunits in numerous natural products and designed molecules with substantial pharmacological properties.Here,a palladium-catalyzed chemodivergent regio-and enantioselective allylic alkylatio...
关键词:asymmetric catalysis allylic alkylation palladium OXAZOLONES chemodivergent 
Developments and applications of allyl-(aza)allyl coupling reactions
《Green Synthesis and Catalysis》2023年第3期190-205,共16页Leiyang Lv Huijun Qian 
supported by the National Natural Science Foundation of China(No.22201300);the Fundamental Research Funds for the Central Universities,and the Research Funds of Renmin University of China(No.21XNLG04).
We have summarized the developments and advancements of allyl-(aza)allyl coupling reactions in the past years.Since the first report in 1980,Pd-catalyzed allyl-allyl couplings have not drawn chemists'much attention fo...
关键词:ALLYLATION Pd catalysis CROSS-COUPLING C-C bond formation C-X bond formation 
Pd-Catalyzed Asymmetric Allylic C—H Functionalization被引量:1
《Chinese Journal of Chemistry》2023年第15期1841-1848,共8页Pu-Sheng Wang Liu-Zhu Gong 
the National Key R&D Program of China(2021YFA1500100);Youth Innovation Promotion Association CAS(2020448);NSFC(22171254 and 22188101);Anhui Provincial Natural Science Foundation(2108085MB58);USTC Research Funds of the DoubleFirst-Class Initiative(YD2060002024);Start-up Research Fund from University of Science and Technology of China(KY2060000216).
Comprehensive Summary Pd-catalyzed asymmetric allylic C—H functionalization has emerged as a powerful tool to access chiral,densely functionalized molecules from easily accessible alkenes,enabling the increase of the...
关键词:C-H activation Asymmetric catalysis ALLYLATION Palladium Allylic compounds Regioselectivity ALKENES 
Palladium-catalyzed base-and solvent-controlled chemoselective allylation of amino acids with allylic carbonates
《Chinese Chemical Letters》2022年第11期4850-4855,共6页Yang Zhou Hang Chen Panpan Lei Chunming Gui Haifeng Wang Qiongjiao Yan Wei Wang Fener Chen 
financial support from the National Natural Science Foundation of China(No.21602144);the Science and Technology Program of Sichuan Province(No.2018JY0485);Scientific Research Project of Education Department of Hubei Province(Nos.Q20211503,B2020057)。
The utilization of readily available amino acids,which is not only an oxygen nucleophile but also a nitrogen nucleophile,in palladium-catalyzed allylic substitution is realized under mild conditions.The chemoselectivi...
关键词:ALLYLATION Amino acid CARBONATES CHEMOSELECTIVITY Palladium 
Ligand-Controlled Palladium-Catalyzed Regiodivergent Defluorinative Allylation of gem-Difluorocyclopropanes viaσ-Bond Activation被引量:2
《Chinese Journal of Chemistry》2022年第19期2345-2355,共11页Lei Wu Minyan Wang Yong Liang Zhuangzhi Shi 
the National Natural Science Foundation of China(Grants 22025104,21972064 and 21901111);the Fundamental Research Funds for the Central Universities for their financial support(Grant 020514380254);The project was also supported by Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University.
Monofluoroalkenes are important and versatile privileged components in pharmacologically relevant molecules.Here,we report a method for the selective construction of these compounds in a diversity-oriented fashion thr...
关键词:ALLYLATION C-C activation CROSS-COUPLING gem-Difluorocyclopropanes DEFLUORINATION 
Asymmetric Catalytic α-Selective Allylation of Ketones with Allyltrifluoroborates Using Dual-Functional Chiral In^(Ⅲ)/N,N'-Dioxide Complex被引量:2
《Chinese Journal of Chemistry》2022年第15期1793-1798,共6页Xiaoxue Tang Zhishan Su Qianchi Lin Lili Lin Shunxi Dong Xiaoming Feng 
This work is supported by the National Natural Science Foundation of China(No.21890723);Sichuan University(2020SCUNL204).
Comprehensive Summary Asymmetric catalytic allylation of halo-substituted ketones and ketoesters was accomplished to yield a number of homoallylic tertiary alcohols in excellent reactivity and enantioselectivity.In th...
关键词:ALLYLATION Potassium allyltrifluoroborate KETONES INDIUM Regioselectivity and enantioselectivity 
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