Ru(II)-Catalyzed ortho C-H Allylation of N-Aryl-7-azaindoles with 2-Methylidene Cyclic Carbonate  

作　　者：Jing Zhang Quan-Jian Luo Han-Chi Wang Jin-Heng Li Bo Sun 

机构地区：[1]State Key Laboratory Base of Eco-Chemical Engineering,College of Chemical Engineering,Qingdao University of Science and Technology Qingdao,Shandong266042,China [2]State key Laboratory of Applied Organic Chemistry,Lanzhou University Lanzhou,Gansu 7300oo,China [3]School of Chemistry and Chemical Engineering,Henan Normal University,Xinxiang,Henan 453007,China

出　　处：《Chinese Journal of Chemistry》2024年第9期985-989,共5页中国化学（英文版）

基　　金：supported by the Natural Science Foundation of Shandong Province(ZR2019BB011);the Scientific Research Foundation of Qingdao University of Science&Technology(010029022).

摘　　要：A Ru(II)-catalyzed ortho allylation reaction of N-aryl-7-azaindole with readily available 2-methylidene cyclic carbonate has been developed.This reaction is an effective pathway for synthesizing 7-azaindole derivatives with a wide scope of substrates and high yields.In addition,the method can be extended to the allylation of other heterocyclic compounds and several cyclic carbonates,highlighting the practicality of this strategy for synthesis.

关 键 词：Ru(II) ALLYLATION N-Aryl-7-azaindoles Cyclic carbonates Heterocyclic compounds C-H activation 

分 类 号：O62[理学—有机化学]