Developments and applications of allyl-(aza)allyl coupling reactions  

作　　者：Leiyang Lv Huijun Qian 

机构地区：[1]Key Laboratory of Advanced Light Conversion Materials and Biophotonics,Department of Chemistry,Renmin University of China,Beijing 100872,China

出　　处：《Green Synthesis and Catalysis》2023年第3期190-205,共16页绿色合成与催化（英文）

基　　金：supported by the National Natural Science Foundation of China(No.22201300);the Fundamental Research Funds for the Central Universities,and the Research Funds of Renmin University of China(No.21XNLG04).

摘　　要：We have summarized the developments and advancements of allyl-(aza)allyl coupling reactions in the past years.Since the first report in 1980,Pd-catalyzed allyl-allyl couplings have not drawn chemists'much attention for almost 20 years.Not until the last two decades,transition-metal-catalyzed allyl-(aza)allyl transformations have been retrieved vital interest and significantly developed in many respects,including metal-catalyst,ligand development,mechanistic understanding,substrate scope,and applications in the preparation of complex functional molecules.This review is organized according to the transition metals used in allyl-allyl coupling reactions including our own work.Besides,transition-metal-free,allyl-azaallyl cross-couplings and applications in the total synthesis of natural products and drugs have also been included.

关 键 词：ALLYLATION Pd catalysis CROSS-COUPLING C-C bond formation C-X bond formation 

分 类 号：O643.36[理学—物理化学]