Catalyzed oxidation of 2,6-dimethylphenol in Triton X-100 micellar solution  

作　　者：Jie Zhu Xiang Guang Meng Hai Dong Wang Shan Dong Liu Qin Hui Pang Juan Du Xian Cheng Zeng 

机构地区：[1]College of Chemistry, Sichuan University, Chengdu 610064, China [2]Bio-Chemistry Experimental Center, Jiaxing College, Jiaxing 314001, China [3]College of Physics Science, Qingdao University, Qingdao 266071, China

出　　处：《Chinese Chemical Letters》2007年第3期349-351,共3页中国化学快报（英文版）

基　　金：This work was supported by the National Natural Science Foundation of China(No.20107004);the Science Foundation of Department of Education of Zhejiang Province(No.20061609).

摘　　要：The oxidative coupling reaction of 2,6-dimethylphenol with H202 catalyzed by a copper（H） Schiff complex in aqueous and Triton X-100 micellar solution under mild conditions was investigated. The kinetics of formation of 3,3＇,5,5＇-tetramethyl-4,4＇- diphenoquinone （DPQ） was studied. Rate constant k2 were obtained. The optimum pH for DPQ generation reaction is 7.25. The main product was DPQ in aqueous buffer solution, but PPE and the oxidized products of PPE remained in Triton X-100 micellar solution.The oxidative coupling reaction of 2,6-dimethylphenol with H202 catalyzed by a copper（H） Schiff complex in aqueous and Triton X-100 micellar solution under mild conditions was investigated. The kinetics of formation of 3,3＇,5,5＇-tetramethyl-4,4＇- diphenoquinone （DPQ） was studied. Rate constant k2 were obtained. The optimum pH for DPQ generation reaction is 7.25. The main product was DPQ in aqueous buffer solution, but PPE and the oxidized products of PPE remained in Triton X-100 micellar solution.

关 键 词：2 6-DIMETHYLPHENOL Oxidative coupling MICELLE KINETICS 

分 类 号：O625.312[理学—有机化学]