甲基丙烯酰氧乙基三甲基氯化铵与丙烯酰胺的合成研究  

Study on synthesis of the methacrylatoethyl trimethyl ammonium chloride and acrylamide

作　　者：潘珺[1] 熊玉宝[1] 

机构地区：[1]长安大学研究生部,陕西西安710054

出　　处：《应用化工》2007年第5期481-483,487,共4页Applied Chemical Industry

摘　　要：丙烯酰胺(AM)与甲基丙烯酰氧乙基三甲基氯化铵(DMC)进行水溶液聚合,考察了引发剂浓度、温度、单体配比、pH值、引发剂等因素对共聚物的阳离子度、特性黏度以及相对分子质量的影响。结果表明,制备高相对分子质量的阳离子型聚丙烯酰胺的最佳工艺条件为:pH为8,温度为50℃,引发剂的用量为0.8 mmol/L,DMC∶AM(摩尔比)=1∶3。The copolymer synthesized in aqueous solution polymerization from methacrylatoethyl trimethyl ammonium chloride（DMC） and acrylamide was studied in this paper. The effects of concentration of initiator,temperature,monomer ratio,pH and initiator on cationic degree of copolymer,intrinsic viscosity and relative mass of molecule were discussed in detail.The optimal conditions are：pH is 8,temperature is 50℃,amount of initiator is 0.8 mmoI/L,DMC：AM is 1：3.At last,we got the optimum technics of the high molecular weight cationic polyacrylamides.

关 键 词：阳离子型聚丙烯酰胺 甲基丙烯酰氧乙基三甲基氯化铵 丙烯酰胺 

分 类 号：X131.2[环境科学与工程—环境科学]