Efficient Synthesis of Octalone  

作　　者：ZHANG Chen CHEN Jin-chun ZHENG Guo-jun LI Yu-lin 

机构地区：[1]State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China

出　　处：《Chemical Research in Chinese Universities》2007年第3期276-279,共4页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China(No20272021)

摘　　要：A highly efficient and convergent approach for the synthesis of octalone 1, the focal intermediate for the synthesis of several sesquiterpenoids, was developed based on the cationic cyclization strategy of the functionalized oxabicyclic template 5.A highly efficient and convergent approach for the synthesis of octalone 1, the focal intermediate for the synthesis of several sesquiterpenoids, was developed based on the cationic cyclization strategy of the functionalized oxabicyclic template 5.

关 键 词：Octalone （± ）-1β 11-Dihydroxy-△^4-eudesmol Cationic cyclization SESQUITERPENOIDS Total synthesis 

分 类 号：O625.42[理学—有机化学]