联二萘酚配合物催化的不对称异原子Diels-Alder反应研究进展  

Study Progress on Hetero-Diels-Alder Reaction Catalyzed by Binaphthol Complexes

作　　者：王伟[1] 段振华[1] 李宝林[1] 

机构地区：[1]陕西师范大学化学与材料科学学院

出　　处：《化学研究》2007年第2期93-97,102,共6页Chemical Research

摘　　要：光学活性的联二萘酚及其衍生物作为优良的手性配体在不对称催化反应中的研究已经取得重大进展,本文概述了近些年来以联二萘酚及其衍生物为手性配体和各种金属盐形成的配合物作为手性催化剂在不对称催化的异原子Diels-Alder反应中的应用.总结了各种基于联二萘酚及其衍生物的用于异原子Diels-Alder反应的新的催化剂,以及能有效不对称催化该反应的新条件及新方法.The study of optical active R-or S-binaphthol and its derivatives as excellent chiral ligands in asymmetric catalytic reaction has obtained significant progress. Various metal complexes of R- or S-binaphthol or its derivatives have been applied in asymmetric catalytic hetreo-Diels-Alder reaction in recent years. New chiral catalysts, new methods and new conditions based on various optical pure binaphthol and derivatives which are effectively used in asymmetric hetreo-Diels-Alder reaction are reviewed.

关 键 词：联二萘酚 异原子Diels-Alder反应 不对称催化 综述 

分 类 号：O621.3[理学—有机化学] TQ243.1[理学—化学]