离子液体催化大豆油制备生物柴油  

Synthesis of biodiesel from soybean oil catalyzed by ionic liquids

作　　者：张磊[1] 于世涛[1] 刘福胜[1] 解从霞[1] 

机构地区：[1]青岛科技大学化工学院,山东青岛266042

出　　处：《工业催化》2007年第7期34-37,共4页Industrial Catalysis

基　　金：国家自然科学基金资助项目(30571463);山东省自然科学基金资助项目(Y2005B07)

摘　　要：制备了对水稳定性好、带—SO3H官能团的咪唑丙烷磺酸硫酸氢盐离子液体,并以其作为催化剂进行了大豆油酯交换反应制备生物柴油的研究。考察了离子液体的用量、醇与油物质的量比、反应温度和反应时间对酯交换反应的影响及离子液体的稳定性。实验结果表明,在n(甲醇)∶n(大豆油)=12∶1、反应温度120℃、反应时间8 h和催化剂用量为原料油质量的4.0%条件下,产物中脂肪酸甲酯收率可达96.5%,且离子液体的稳定性好,可循环使用。An ionic liquid stable in water, 1-（3-sulfonic acid） propyl-imidazole hydrosulfate with an alkanesulfonic acid group, was prepared. Synthesis of biodiesel from soybean oil catalyzed by the ionic liquidwas studied. Effects of ionic liquid dosage, molar ratio between methanol and soybean oil, reaction temperature and reaction time on the transesterification reaction and stability of the ionic liquid were investigated. Optimal transesterification condition was obtained as follows： n（methanol） ： n（soybean oil） = 12 ： 1, reaction temperature 120 ℃, reaction time 8 h, dosage of ionic liquid =4.0% of the oil weight. Mass fraction of fatty acid methyl ester of 96.5% was obtained in the product under the optimal condition. The ionic liquid was stable and could be repeatedly used.

关 键 词：离子液体 酯交换 大豆油 生物柴油 

分 类 号：TE667[石油与天然气工程—油气加工工程] TQ426.99[化学工程]