含有氨基酸基Schiff碱配体的锌、镍配合物的合成、结构及热分解动力学研究  

Syntheses,Crystal Structures and Decomposition Kinetics of Complexes of Zinc and Nickel with Amido-Schiff-base as the Ligand

作　　者：韩晶[1] 邢永恒[1] 张兴晶[2] 周光华[2] 安悦[2] 葛茂发[2] 

机构地区：[1]辽宁师范大学化学化工学院,大连116029 [2]中国科学院化学研究所,北京100080

出　　处：《高等学校化学学报》2007年第8期1431-1433,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:20571036);辽宁省教育基金(批准号:05L212)资助

摘　　要：Two new complexes,C9H7NO3)Zn(C3H4N2)2(1) and(C9H7NO3)Ni(C3H4N2)2(C4H5N2O)·CH3OH·0.5H2O(2),with salicylideneglycinyl as the ligands,were synthesized successfully at room temperature in methanol solution,and characterized via elemental analyses,IR spectra,UV-Vis and fluorescence spectra,and X-ray diffraction and thermogravimetric analyses were also carried out.Two new complexes, C9 H7 NO3 ） Zn （ C3 H4 N2 ）2 （ 1 ） and （ C9 H7 NO3 ） Ni（ C3 H4 N2 ）2 （ C4 H5 N2 O） · CH3OH ·0. 5H2O（2） , with salicylideneglycinyl as the ligands, were synthesized successfully at room temperature in methanol solution, and characterized via elemental analyses, IR spectra, UV-Vis and fluorescence spectra, and X-ray diffraction and thermogravimetric analyses were also carried out.

关 键 词：水杨醛氨基乙酸配体 锌配合物 镍配合物 晶体结构 非等温热分解动力学 

分 类 号：O614[理学—无机化学] O641[理学—化学]