磺化水杨醛缩苯胺含Cu配合物的合成表征及催化性质研究  

Synthesis Characterization and Catalytic Activity of Complexes of Salicylaldehyde-aniline with Cu

作　　者：吴雪梅[1] 董健媛[1] 杨帆[1] 梁燕[1] 单永奎[1] 

机构地区：[1]华东师范大学化学系,上海200062

出　　处：《化学世界》2007年第8期456-459,共4页Chemical World

摘　　要：合成了以磺化水杨醛缩苯胺为配体的含铜配合物,并通过红外光谱,元素分析手段表征了该配合物。通过紫外可见光谱法考察了该化合物对抗坏血酸在空气中氧化反应的催化作用及在瓜环存在条件下的催化性能。结果表明,该配合物对抗坏血酸在空气中氧化具有良好的催化性能,加入瓜环后,催化性能有所提高。Complexes of salicylaldehyde-aniline, with Cu were synthesized and their structure was characterized by IR and elemental analysis. The catalytic activity Of the complexes for the oxidation of Ve in air was investigated, and it the catalytic activity was improved by cucurbiturils.

关 键 词：磺化水杨醛缩苯胺 配合物 瓜环 抗坏血酸 催化作用 

分 类 号：O614.12[理学—无机化学]