单、双季戊四醇的合成工艺研究  

Study on the Synthesis of Pentaerythritol and Dipentaerythritol

作　　者：张健伟[1] 赫广田[2] 

机构地区：[1]大庆石油学院化学化工学院,大庆163318 [2]大庆石油学院机械科学与工程学院,大庆163318

出　　处：《天然气化工—C1化学与化工》2007年第5期40-42,46,共4页Natural Gas Chemical Industry

摘　　要：通过单因素实验,考察了反应温度、反应时间、甲醛与乙醛的配比等因素对单、双季戊四醇收率的影响。利用正交实验确定了合成单、双季戊四醇的最佳反应条件。在此工艺条件下,单、双季戊四醇的收率均在20%以上。The regularities of the influence of various factors includingreaction temperature, reaction time, the ratio of formaldehyde to acetaldehyde, the quantity of alkali and the concentration of formaldehyde on the yieldsof pentaerythritol and dipentaerythritol were studied. The orthogonal design was carried out to determine the optimum reaction parameters forthe synthesis of pentaerythritoland dipentaerythritol. The yieldsof pentaerythritol and dipentae- rythritol were above 20percent under the optimum reaction oarameters.

关 键 词：单季戊四醇 双季戊四醇 正交实验 甲醛 乙醛 

分 类 号：TQ223.164[化学工程—有机化工]