糖类研究(XVI)──大环化合物Clemochinenoside-A前体的合成  

Studies on Carbohydrates (XVI)──Synthetic Study on the Precursor of Macrocyclic Compound Clemochinenoside-A

作　　者：毛建民[1] 陈宏明[1] 蔡孟深[1] 

机构地区：[1]北京医科大学药学院,北京100083

出　　处：《高等学校化学学报》1997年第1期82-84,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金

摘　　要：Herein we wlsh to report the synthetic study on the precursor (10) of clemochi-nenoside-A(1), a new kind of macrocyclic glycoside, which was found in the roots of Clem-atics chinesis Osbeck (wei ling xian) that was used as Chinese herbal medicine for treatment of anthritis, arthralgia, headache and inflarnmation. The key steps were stereoselective gly-cosidation of 6 and selective mesylation of 9. Further studies are still going on,Herein we wlsh to report the synthetic study on the precursor (10) of clemochi-nenoside-A(1), a new kind of macrocyclic glycoside, which was found in the roots of Clem-atics chinesis Osbeck (wei ling xian) that was used as Chinese herbal medicine for treatment of anthritis, arthralgia, headache and inflarnmation. The key steps were stereoselective gly-cosidation of 6 and selective mesylation of 9. Further studies are still going on,

关 键 词：单糖 前体 合成 立体选择性合成 大环化合物 

分 类 号：O629.112[理学—有机化学]