氮气流量对CIGS薄膜结构和形貌的影响  

Influences of N_2 flux on microstructure and morphologies of CIGS films

作　　者：韩东麟[1] 张弓[1] 庄大明[1] 沙晟春[1] 元金石[1] 

机构地区：[1]清华大学机械工程系,北京100084

出　　处：《功能材料》2008年第3期446-448,452,共4页Journal of Functional Materials

基　　金：国家高技术研究发展计划(863计划)资助项目(2004AA513023)

摘　　要：采用中频交流磁控溅射方法,在Mo层上沉积了CuInGa(CIG)预制膜。以N2为载气,采用固态硒化法制备获得了Cu(In1-xGax)Se2(CIGS)吸收层薄膜,考察了N2流量对CIGS薄膜结构和形貌的影响。采用SEM和EDS观察和分析了薄膜的表面形貌和成分,采用XRD表征了薄膜的组织结构。结果表明,在不同的N2流量下制备的CIGS薄膜,均具有单一的黄铜矿相结构,薄膜具有(112)面的择优取向。当Ar流量为0.40m3/h时,薄膜表面结构致密,晶粒大小均匀,并且Cu、In、Ga原子含量,处于制备弱p型CIGS薄膜的理想范围。In this work, CuInGa （CIG） precursors were deposited on the substrate of Mo-coated glass with mid- dle frequency a. c. magnetron sputtering by alternately sputtering Culn and CuGa targets. Then the Cu（In1-x Gax）Se2（CIGS） absorbers were obtained by selenizing the CIG precursors in the atmosphere of Se vapor and carrier gas of N2. The CIGS films were characterized with X-ray diffraction, scanning electron microscopy, and energy dispersive spectroscopy to evaluate the microstructure, morphology, and composition, respectively. The effects of N2 flux on the microstructure and morphologies were investigated. The results show that the microstructure of the CIGS films is mainly of ehaleopyrite phase with a （112） preferred orientation at various N2 flux. The surface of CIGS thin film is the densest with uniform grain size at the N2 of 0.40m^3/h. And the atomic ratios of Cu, In and Ga are in an ideal range for a CIGS film with weak p-type, which was obtained at the N2 flux of 0.40m^3/h.

关 键 词：太阳能电池 CIGS 磁控溅射 薄膜 硒化 

分 类 号：TM615[电气工程—电力系统及自动化]