手性席夫碱配合物用于催化不对称环氧化  

Chiral Schiff Base Complexe Catalyst for the Asymmetric Epoxidation

作　　者：柴凤兰[1] 王向宇[1] 陶京朝[1] 

机构地区：[1]郑州大学化学系,郑州450052

出　　处：《化学进展》2008年第2期300-311,共12页Progress in Chemistry

基　　金：河南省杰出人才创新基金项目(No.0221001200)资助

摘　　要：手性席夫碱过渡金属配合物可以高效催化烯烃不对称环氧化反应,因此其合成及催化性能研究一直以来受到广泛的关注。本文较详细地综述了最近十年来合成的手性席夫碱过渡金属配合物及其对烯烃环氧化反应的催化性能的研究进展。重点讨论了新型的对称和非对称salen型配体过渡金属配合物的合成及其应用,分析探讨了手性席夫碱过渡金属配合物作为催化剂的优缺点、催化机理和未来发展方向。The study on synthesis of the chiral Schiff base transition metal complexes and their catalytic performance has attracted more attentions due to their applications in the asymmetric epoxidation of olefins. This article summarises some recent results on the chiral Schiff base transition metal complexes and their catalytic applications in the asymmetric epoxidation of olefins, including the synthesis and the activities of several novel Schiff base transition metal complexes. Catalytic mechanism and perspective of the chiral Schiff base transition metal complexes including their predominance and disadvantages are also discussed.

关 键 词：手性席夫碱 过渡金属配合物 烯烃 不对称环氧化 

分 类 号：O621.34[理学—有机化学]