Cu(OAc)_2·H_2O与氨基酸固相配位化学反应动力学的电导法研究  

STUDIES ON THE KINETICS OF SOLID STATE REACTION BETWEEN Cu(OAc) 2·H 2O AND GLYCINE OR α-ALAINE BY USING THE ELECTRICAL CONDUCTIVITY METHOD

作　　者：贾殿增[1] 庄稼[2] 忻新泉[3] 

机构地区：[1]新疆大学化学系 [2]西南工学院材料科学系 [3]南京大学化学系

出　　处：《化学研究与应用》1997年第3期245-249,共5页Chemical Research and Application

摘　　要：用恒温电导法研究了Ｃｕ（ＯＡｃ）２·Ｈ２Ｏ与甘氨酸、丙氨酸在低加热温度条件下的固－固相配位化学反应，探讨了可能的动力学机理，并计算出两固相反应的动力学参数，用元素分析、Ｘ射线粉末衍射、红外光谱等表征了固相反应产物。The kinetics of solid state reaction between Cu(OAc) 2·H 2O and glycine or α ananine were investigated by electrical conductivity method at various temperatures.Possible mechanism was suggested and discussed and kinetic parameters were consequently calculated.The solid products were characterized by elemental analysis,XRD and IR.

关 键 词：固相反应 氨基酸 铜配合物 动力学 配位化学 

分 类 号：O614.121[理学—无机化学] Q517.02[理学—化学]