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作 者:Ming Zhou Zheng-wu Wang Zu-min Xu
机构地区:[1]Department of Food Science and Technology, School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China [2]School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China
出 处:《Chinese Journal of Chemical Physics》2008年第2期131-135,共5页化学物理学报(英文)
基 金:This work was supported by the National Natural Science Foundation of China (No.20676051 and No.20573048) and the Important Construction Project (category A) of Shanghai Jiao Tong University (No.AE150085).
摘 要:By introducing the functional theory into the calculation of electric double layer (EDL) interaction, the interaction energies of two parallel plates were calculated respectively at low, moderate, and high potentials. Compared with the results of two existing methods, Debye-Hückel and Langmuir methods, which are applicable just to the critical potentials and perform poorly in the intermediate potential, the functional approach not only has much simpler expression of the EDL interaction energy, but also performs well in the entire range of potentials.
关 键 词:Interaction energy Functional theory Electric double layer Parallel plate
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