利用UDMH合成胺基酰亚胺化合物的研究进展  

Review on Aminimide Compounds Synthesized by UDMH

作　　者：李正莉[1] 张有智[1] 王煊军[1] 樊瑞君[1] 

机构地区：[1]第二炮兵工程学院,陕西西安710025

出　　处：《含能材料》2008年第4期469-473,共5页Chinese Journal of Energetic Materials

摘　　要：回顾了国外近十年来关于利用偏二甲肼(UDMH)合成胺基酰亚胺(aminimide或aminemide)化合物的研究进展。分析了胺基酰亚胺化合物的热解、光解、聚合等主要化学性质,探讨并比较了其热解和光解机理。总结了该化合物用于合成潜伏性固化剂、表面活性剂、分子识别剂及药物等领域的研究现状。分析表明该化合物在上述领域具有推广前景,是废弃UDMH再利用的一条有效途径。The main development directions of aminimide compounds synthesized by unsymmertrical dimethyl-hydrazine （UDMH） during the past decade were reviewed. The main chemical properties of aminimides, such as pyrolysis, photolysis and polymerization, were analyzed. The mechanism of pyrolysis was compared with that of photolysis. The applications of aminimides in latent curing agents, surfactants, molecular identification and drugs were summarized. Results show that the preparation and applications of aminimides are an effective approach to reclaim scrap UDMH.

关 键 词：有机化学 偏二甲肼(UDMH) 胺基酰亚胺 潜伏性固化剂 表面活性剂 分子识别 

分 类 号：TQ564[化学工程—炸药化工]