Rm·M(dmit)_2型有机金属配合物的合成与表征  

Synthesis and Characterization of Bis(1,3 dithiole 2 thione 4,5 dithiolate)metal tetraalkylammonium complexes

作　　者：李洪启[1,2] 宋燕西[1,2] 周宏英[1,2] 王爱勤 谭干祖[1,2] 姚钟麒 

机构地区：[1]中国科学院兰州化学物理研究所 [2]兰州大学化学系

出　　处：《合成化学》1997年第2期165-167,共3页Chinese Journal of Synthetic Chemistry

摘　　要：合成了２个系列９种新的季铵·二（１，３－二硫杂环戊烯－２－硫酮－４，５－二巯基）金属［缩写为Ｒｍ·Ｍ（ｄｍｉｔ）２］型有机金属配合物。用元素分析、ＩＣＰ和１ＨＮＭＲ等对它们的结构进行了表征，并讨论了光谱特征。Nine new complexes[R m·M(dmit) 2] of bis(1,3 dithiole 2 thione 4,5 dithiolate)metal tetraalkylammonium were synthesized. Their compositions were determined by elemental analysis, ICP and 1H NMR spectra. IR and UV spectra of the complexes were also measured and discussed.

关 键 词：DMIT 配合物 金属有机配合物 硫酮 二硫杂环戊烯 

分 类 号：O614[理学—无机化学]