甲磺隆结合残留对土壤酶活性的影响  

Effects of Bound Residues of Metsulfuron-Methyl on Soil Enzymatic Activities

作　　者：李兆君[1,2] 徐建明[2] 梁永超[1,3] 汪海珍[2] 马国瑞[2] 

机构地区：[1]中国农业科学院农业资源与农业区划研究所农业部作物营养与施肥重点实验室,北京100081 [2]浙江大学土水资源与环境研究所浙江省亚热带土壤与植物营养重点研究实验室,杭州310029 [3]石河子大学农学院新疆生产建设兵团绿洲生态农业重点实验室,石河子832003

出　　处：《生态毒理学报》2008年第5期499-506,共8页Asian Journal of Ecotoxicology

基　　金：国家杰出青年科学基金项目(No.40425007);国家自然科学基金项目(No.40701163);中央级公益性科研院所基本科研业务费专项资金中国农业科学院农业资源与农业区划研究所所长基金项目(No.2007-30)

摘　　要：为了研究甲磺隆结合残留对土壤酶活性的影响,将黄粉土（水稻土）经甲磺隆结合残留处理98天,检测土壤脲酶、酸性磷酸酶、过氧化氢酶和蔗糖酶活性.结果表明,甲磺隆结合残留对土壤酶活性的影响不仅与甲磺隆结合残留处理浓度和培养时间有关,同时还与土壤酶种类有关.培养前期（第14天前）,甲磺隆结合残留对土壤酸性磷酸酶和过氧化氢酶具有抑制作用,而对土壤脲酶和蔗糖酶的影响则表现为低浓度时激活,高浓度时抑制;培养后期（第14天后）,甲磺隆结合残留对土壤脲酶、酸性磷酸酶和过氧化氢酶具有激活作用,在一定浓度范围内（0.050-0.281mg·kg^-1）对土壤蔗糖酶也具有一定激活作用;就土壤酶而言,在污染早期,土壤过氧化氢酶对甲磺隆结合残留较敏感,可以作为表征甲磺隆结合残留土壤污染的生物活性指标.In order to investigate effects of bound residues of metsulfuron-methyl（BR） on the activities of soil enzymes, the activities of urease, acid phosphatase, catalase, and sucrase were determined in Huangfentu（rice soil）spiked with bound residues of metsulfuron-methyl for 98 days. Effects of BR in soil on soil enzymatic activities depended not only on the level of BR treatments and the time when BR stayed in soil, but also on the soil enzyme types. In the earlier period of incubation（before 14 days）, BR could inhibit the activities of acid phosphatase and catalase, however could activate and inhibit the activities of urease and sucrase at the low level and at the high level, respectively. In the later period of incubation（after 14 days）, BR could activate the activities of urease, acid phosphatase, and catalase at all the levels. BR could also activate the sucrase activity at the level of 0.050 to 0.281mg·kg^-1. In terms of soil enzymes, catalase was more sensitive to bound residues of metsulfuron-methyl than other soil enzymes, and could be taken as the indicator to indicate the microbial activities of soils contaminated by BR.

关 键 词：甲磺隆 结合残留 土壤酶活性 

分 类 号：X171.5[环境科学与工程—环境科学]