饮用水中典型致嗅物质去除技术研究  

Removal Technology of Typical Odorant in Drinking Water

作　　者：李勇[1] 陈超[1] 张晓健[1] 刘尧[1] 张晓慧[2] 朱晓辉[2] 戴吉胜 许欢 

机构地区：[1]清华大学环境科学与工程系,北京100084 [2]兰州交通大学环境与市政工程学院,兰州730070 [3]东莞市东江水务有限公司,东莞523112

出　　处：《环境科学》2008年第11期3049-3053,共5页Environmental Science

基　　金：国家自然科学基金项目(50778097);国家科技支撑计划项目(2007BAC26B03)

摘　　要：为去除某市饮用水中的嗅味,根据该市饮用水水源中致嗅物质的组成特点,采用氧化、吸附和臭氧活性炭对其中典型致嗅物质的去除效果及工艺选择进行了研究.结果表明,硫醇硫醚类物质可以用氧化法有效去除,对土嗅素(geosmin)和2-甲基异莰醇(2-MIB)采用氧化法和活性炭吸附法均有效,但吸附法的效果更好;当原水中硫醇、硫醚类致嗅物质浓度<20μg/L,不含有其他类型致嗅物质时,可以采用强化混凝+高锰酸钾氧化工艺去除;当原水中geosmin、2-MIB等微生物代谢产物类致嗅物质浓度<30 ng/L,不含有硫醇硫醚类致嗅物质时,可以采用强化混凝+粉末活性炭吸附工艺去除;当原水中硫醇、硫醚类致嗅物质浓度>20μg/L,geosmin、2-MIB浓度>30 ng/L时,需要增加臭氧活性炭深度处理工艺;当原水中硫醇、硫醚类致嗅物质浓度>150μg/L,或者土嗅素、2-MIB的浓度>100 ng/L时,需要根据致嗅物质组成特点,选择预KMnO4氧化或者粉末活性炭吸附+臭氧活性炭深度处理的组合工艺去除.To eliminate the odor in drinking water of one City in China, a study was performed on the typical odorant removal technology and removal processes. Its results showed that as typical odorants, ethanethiol was effectively removed by oxidation and geosmin and 2-MIB were removed by both oxidation and adsorption, but geosmin and 2-MIB＇s adsorption effect was better than oxidation. When thiol and thioether in raw water was less than 20 μg/L, furthermore, there was not any other odorant, potassium permanganate oxidation should be equipped with enhanced coagulations. When geosmin and 2-MIB in raw was less than 30 ng/L, activated carbon adsorption should be equipped with enhanced coagulations. When thiol and thioether in raw water was more than 20 μg/L, or geosmin and 2-MIB was more than 30 ng/L, ozone-activated carbon process should be added after the conventional water treatment process. When thiol and thioether in raw water was more than 150μg/L, or geosmin and 2-MIB was more than 100 ng/L, preoxidation or adsorption of powder activated carbon at intake should be combined with ozoneactivated carbon according to the odorant composing.

关 键 词：饮用水 嗅味 乙硫醇 土嗅素 2-甲基异莰醇 

分 类 号：X522[环境科学与工程—环境工程] TU991.21[建筑科学—市政工程]