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作 者:余强[1,2,3] 罗逸[2] 袁振宏[1] 杜文鹤[2] 袁国保[4]
机构地区:[1]中国科学院广州能源研究所中国科学院可再生能源与天然气水合物重点实验室,广东广州510640 [2]华中科技大学化学与化工学院,湖北武汉430074 [3]中国科学院研究生院,北京100039 [4]湖北省种子集团公司,湖北武汉430070
出 处:《生物质化学工程》2008年第6期19-22,共4页Biomass Chemical Engineering
摘 要:介绍了一种用于制备水稻直播种纸的生物质胶黏剂,并对其合成工艺进行了研究。通过对玉米淀粉进行糊化、氧化、交联等化学改性,并以碱性稻草浆作为添加剂,研制出满足使用要求的生物质胶黏剂。探讨了氧化剂及交联剂对胶黏剂性能的影响,得出合成工艺条件为:氧化温度为50℃,氧化时间为120 min,氧化剂用量为6%(占淀粉的质量分数),交联剂与淀粉的质量比为2∶5,并对产物结构的红外光谱特征进行了分析。最后育种试验表明胶黏剂对种子生长无毒害作用。A kind of bio-based adhesive used for making the rice seeding sheet and its synthesizing process were introduced. The bio-based adhesive which met the requirement was prepared from starting material corn starch which was first modified by cooking with alkaline pulps, then oxidation and cross-linking. The influences of reaction temperature and time, dosage of oxidizer and cross-linkier on the properties of the adhesive were discussed. The synthesis condition was: oxidation temperature, 50 ℃; oxidation time,120 min ; oxidizer dosage, 6 % (based on starch) and mass ratio of cross-linkier to starch, 2 : 5. The structure of the adhesive was characterized with IR. At last, the breeding test shown that there was no negative impact on the germination of seeds when using the adhesive.
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