含苯并噻唑基的硫桥杯[4]芳烃衍生物的合成及结构  

Synthesis and Structure of p-tert-Butylthiacalix[4] arene Derivatives Containing Benzothiazole Groups

作　　者：赵邦屯[1] 丁静静[2] 渠桂荣[2] 

机构地区：[1]洛阳师范学院化学系,洛阳471022 [2]河南师范大学化学与环境科学学院,新乡453002

出　　处：《高等学校化学学报》2008年第12期2549-2553,共5页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:20872058)资助

摘　　要：在碳酸钾存在下,对叔丁基硫桥杯[4]芳烃(1)分别与端基二溴代烷和碘甲烷反应,生成硫桥杯[4]芳烃衍生物2和3,它们分别与过量的2-巯基苯并噻唑在碳酸钾存在下反应,生成含苯并噻唑基的硫桥杯[4]芳烃衍生物5a～5d.通过1HNMR,13CNMR,IR,MS和元素分析等手段对产物进行了表征.同时,采用X射线衍射分析确定了硫桥杯[4]芳烃5b的晶体结构.p-tert-Butylthiacalix[4]arene（1）was alkylated with methyl iodide or dibromoalkane to obtain thiacalix[4]arene intermediates 2 and 3 with the aid of potassium carbonate,respectively.A series of p-tert-butylthiacalix[4]arene derivatives 5a-5d which append benzothiazol-2-ylthio groups at the lower rims were easily synthesized in good yields by the reaction of thiacalix[4]arene intermediates 2 or 3 with 2-mercapto-benzothiazole in the presence of potassium carbonate.All the crystal novel compounds were characterized by 1H NMR,13C NMR,IR,MS and elemental analysis.Meanwhile,the structure of thiacalix[4]arene 5b was identified by X-ray diffraction analysis.

关 键 词：芳烃 2-巯基苯并噻唑 合成 晶体结构 

分 类 号：O621.3[理学—有机化学] O621.7[理学—化学]