(Z)-1-[2-(二苯基碘化锡基)乙烯基]-1-环己醇的合成、晶体结构和性质  

Synthesis,Crystal Structure and Properties of (Z)-l-[2-(Bisphenyl-Iodine-Stannyl) Vinyl]-1-Cyclohexanol

作　　者：朱东升[1] 戴慧聪[1] 单希林[2] 田来进 傅芳信[1] 潘华德[1] 邢彦[3] 林永华 

机构地区：[1]东北师范大学化学系,长春130024 [2]黑龙江省安达市大庆石油学院化工系,151400 [3]中国科学院长春应化研究所,长春130022

出　　处：《有机化学》1998年第2期162-165,共4页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金

摘　　要：报道了标题化合物的合成、晶体结构及性质。该晶体属于单斜晶系,空间群为P2_1,晶胞参数a=0.9255(3)nm,b=1.0504(3)nm,c=1.0217(3)nm,β=100.99(2)°,V=0.9750nm^3,Z=2,D_c=1.790g/cm^3,R=0.025,晶体结构由直接法解出。标题化合物分子中的锡原子被配体的三个碳、一个碘和一个氧原子配位;配位原子是畸变的三角双锥构型;标题化合物具有与卤素发生取代反应而不发生加成反应的性质。Synthesis, crystal structure and properties of title moleculeare discribed. This crystal is monoclinic, belonging to space group P21 with a = 0. 9255(3) ,6 = 1. 0504(3) , c - 1. 0217(3)nm, P = 100.99(2), V = 0.9750nm3, Z = 2, Dc = 1. 790g/cm3, R=0.025. The structure was solved by direct method. The tin atom of the title molecule exists in a distorted- trigonal- bipyramidal geometry, defined by three carbon,one iodineand one oxygen atoms leading to a five - membered chelate ring. The x- ray analysis show that the title compound has the properties of substitution reaction with halogen rather than addition reaction.

关 键 词：环己醇衍生物 有机锡 晶体 抗癌活性 

分 类 号：O627.42[理学—有机化学]