Ultrasound-assisted Highly Efficient Reduction of Nitroarenes to Corresponding N-Arylhydroxylamines  

作　　者：SHI Qi-Xun LU Rong-wen HAO Xin-yu LU Lian-hai ZHANG Shu-fen 

机构地区：[1]State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, P. R, China

出　　处：《Chemical Research in Chinese Universities》2009年第2期183-188,共6页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China(No.20676020);the Program for Changjiang Scholars and Innovative Research Team in Universities of China(No.IRT0711).

摘　　要：A convenient, environmentally benign, and highly efficient protocol for the preparation of N-arylhydroxylamines from the corresponding nitroarenes in a Zn/HCOONH4/CH3CN system under ultrasound is described The advantages of the present method include high chemoselectivity, simple and practical work-up procedure and high yield.A convenient, environmentally benign, and highly efficient protocol for the preparation of N-arylhydroxylamines from the corresponding nitroarenes in a Zn/HCOONH4/CH3CN system under ultrasound is described The advantages of the present method include high chemoselectivity, simple and practical work-up procedure and high yield.

关 键 词：Arylhydroxylamines ULTRASOUND REDUCTION NITROARENES CHEMOSELECTIVITY 

分 类 号：O621.3[理学—有机化学] TB559[理学—化学]