The electrocatalytic synthesis of imines through the reductive imination of nitroarenes with aldehydes is a facile,environmentally friendly,and valuable process.In this study,high selectivity electrosynthesis of imine...
supported by the National Key R&D Program of China(2022YFA1506000);the National Natural Science Foundation of China(22105110,22109110,22206094);the Natural Science Foundation of Shandong Province(ZR2021QB162,ZR2023YQ014);the Youth Innovation Team Project of Shandong Provincial Education Department(022KJ143);the Taishan Scholar Youth Expert Program in Shandong Province(tsqn202211122);the Gusu Innovation and Entrepreneurship Leading Talents Program(ZXL2022497);the Jiangsu Distinguished Professor Program;the Natural Science Foundation of Jiangsu Province(BK20210698)。
The solvolysis of ammonia borane(AB)and the hydrogenation of nitroarenes represent significant reactions for hydrogen generation and value-added chemical synthesis.The strategic engineering of the catalysts is imperat...
financial support from the National Natural Science Foundation of China(22061041);Key Project of Science&Technology of Shaanxi Province(2023-YBGY-430);Project of Science&Technology Bureau of Yulin City(CXY-2022-185);Doctoral Research Foundation of Yan'an University(YDBK2019-60);the Training Program of Innovation and Entrepreneurship for Undergraduates of Yan'an University(D2022077);Research Program of Yan'an University(YDY2020-61);the Youth Innovation Team Project of Shaanxi Provincial Education Department(No.23JP193);National Science Foundation of Shaanxi Province(S2023-JC-QN-0079).
Herein,we present a method for the homogeneous hydrogenation of nitroarenes to produce anilines using low catalyst loading(1 mo%)of copper N-heterocyclic carbene complexes as the catalyst and ammonia borane as the sou...
support from the National Natural Science Foundation of China(grant nos.22021002,22020102005,and 22022705);the CAS-Croucher Funding Scheme for Joint Laboratories.
The direct cleavage of C–NO_(2)bonds for reductive denitration of nitroarenes remains a challenging transformation in synthetic organic chemistry.Herein,we report a biocompatible palladium-deposited graphdiyne nanoca...
National Key Research and Development Program of China(2022YFA1503200,2021YFC2101901);the National Natural Science Foundation of China(22122103,22101130,22001117,21971108,22271144);Fundamental Research Funds for the Central Universities(020514380304,020514380252,020514380272)for financial support.
In this paper,we have developed a decarboxylative amination of carboxylic acids with nitroarenes for the synthesis of secondary amines.The protocol is performed at mild conditions without the use of noble metals as ca...
supported by the National Natural Science Foundation of China(Nos.22061017 and 21862006);Science and technology program of Gansu Province(Nos.22YF7GG127 and 23JRRG0002);Hexi University Research Start-up Fund Project(Nos.KYQD2020013).
Single-atomic catalysts(SACs)caught considerable attention due to their unique structural properties,complete exposed active site,and 100%atom utilization efficiency with remarkable catalytic activity.Mesoporous singl...
supported financially by the National Natural Science Foundation of China(Nos.52236010,51876209,51876210 and 51906247);the Fundamental Research Funds for the Central Universities(No.2242022R10058)。
Inhibiting the side reactions while promoting hydrogenation are the main target for the production of functional anilines from nitroarenes;consequently,the preparation of an ideal catalyst to improve chemical selectiv...
National Natural Science Foundation of China(Nos.21776129 and 21706121);Natural Science Foundation of Jiangsu Province(No.BK20170995);Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX211171);the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)。
Metal-free carbon catalysts with excellent conduction performance have drawn much research attention in reduction reactions.Herein,a N,B co-doped carbon catalyst with high pyrrolic N proportion(35.75%)and excellent su...
Research into environmentally friendly strategies for hydrogen transfer reduction is increasing, along with the need for more elaborate heterocyclic platforms. Within this context, we develop a new approach for substi...
supported by the National Natural Science Foundation of China(21602096)。
A simple electrochemically mediated method for the conversion of nitroarenes to aryl boronic esters is presented.Electrochemical borylation of a diverse range of nitroarenes,including the late-stage borylation of bioa...