Decarboxylative Amination with Nitroarenes via Synergistic Catalysis  

作　　者：Meiling Ding Sitian Zhou Shunruo Yao Chengjian Zhu Weipeng Li Jin Xie 

机构地区：[1]State Key Laboratory of Coordination Chemistry,Jiangsu Key Laboratory of Advanced Organic Materials,Chemistry and Biomedicine Innovation Center(ChemBIC),School of Chemistry and Chemical Engineering,Nanjing University,Nanjing,Jiangsu,210023 China [2]Green Catalysis Center,and College of Chemistry,Zhengzhou University,Zhengzhou,Henan,450001 China

出　　处：《Chinese Journal of Chemistry》2024年第4期351-355,共5页中国化学（英文版）

基　　金：National Key Research and Development Program of China(2022YFA1503200,2021YFC2101901);the National Natural Science Foundation of China(22122103,22101130,22001117,21971108,22271144);Fundamental Research Funds for the Central Universities(020514380304,020514380252,020514380272)for financial support.

摘　　要：In this paper,we have developed a decarboxylative amination of carboxylic acids with nitroarenes for the synthesis of secondary amines.The protocol is performed at mild conditions without the use of noble metals as catalysts.A wide range of structurally diverse secondary amines could be obtained in good yields(up to 94%)with good functional group tolerance.This transformation shows good to excellent selectivity,avoiding the generation of over alkylated byproducts.

关 键 词：NITROARENES AMINES Synergistic catalysis Carboxylic acids Radical alkylation AMINATION PHOTOCATALYSIS Steric hindrance 

分 类 号：O62[理学—有机化学]