广州市大气典型羰基化合物碳同位素组成初探  

THE PRELIMINARY STUDY OF CARBON ISOTOPIC COMPOSITIONS OF ATMOSPHERIC TYPICAL CARBONYL COMPOUNDS IN GUANGZHOU

作　　者：郭送军[1,2] 文晟[1] 谭吉华[3] 王新明[1] 盛国英[1,4] 傅家谟[1,4] 

机构地区：[1]中国科学院广州地球化学研究所有机地球化学国家重点实验室广东省环境资源利用与保护重点实验室,广州510640 [2]中国科学院研究生院,北京100049 [3]清华大学环境科学与工程系,北京100084 [4]上海大学环境与化学工程学院环境污染与健康研究所,上海200072

出　　处：《环境化学》2009年第2期272-275,共4页Environmental Chemistry

基　　金：中国科学院知识创新工程重要方向项目(No.KZCX2-YW-403);国家自然科学基金(No.40503001);973计划基金资助项目(No.2002CB410803);广东省重点基金资助项目(No.40590392)资助

摘　　要：采用气相色谱/燃烧/同位素比值质谱(GC/C/IRMS)技术,通过2,4-二硝基苯肼(DNPH)衍生化方法,初步测定了广州市城区交通主干线大气中甲醛、乙醛和丙酮的碳同位素组成.结果表明,甲醛的δ13C值变化范围为-42.06‰—-33.52‰,乙醛的δ13C值变化范围为-35.84‰—-32.20‰,丙酮的δ13C值变化范围为-30.85‰—-29.50‰;而且,白天相对于夜晚而言,甲醛、乙醛和丙酮的最大碳同位素分馏分别为6.65‰,3.27‰和0.75‰,碳同位素分馏上的差异表明它们在环境大气中不同化学活性上的差异.Carbon isotopic compositions of atmospheric typical carbonyl compounds （ including formaldehyde, acetaldehyde, and acetone） in Guangzhou city were measured by gas chromatography/combustion/isotope ratio mass spectrometry （GC/C/IRMS） through carbonyls via 2,4-dinitrophenylhydrazine derivatizations. Ambient samples were taken above two traffic main lines in Guangzhou. Isotopic data of ambient formaldehyde was found to be in a wide range of -42. 06‰ to -33.52‰. In contrast, δ^13C values of ambient acetaldehyde and acetone varied in a small range （ -35.84‰ to -32. 20‰ and -30. 85‰ to -29. 50‰, respectively） . Further- more, the ambient data measured in the daytime generally showed heavier values than those measured in the nighttime. Averagely, the isotopic data in the daytime were enriched maximally in δ^13C by 6. 65‰, 3.27‰ and 0. 75‰ for ambient formaldehyde, acetaldehyde, and acetone, respectively, suggesting different fractionations during different chemical processes in the atmosphere.

关 键 词：羰基化合物 气相色谱/燃烧/同位素比值质谱 碳同位素 广州市 

分 类 号：X51[环境科学与工程—环境工程]