High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene  

作　　者：Qian CHENG Takayuki ORITANI Alfred HASSNER (Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultural Science, Tohoku University, 1-1 Tsutsumidori-Amamaiyamachi, Aoba-ku,Sendai 981 -8855, Japan)(Department of 

出　　处：《Chinese Chemical Letters》1999年第8期629-632,共4页中国化学快报（英文版）

摘　　要：Modest to high diastereoselectivites have been observed in the conjugate addition of functionalized alcohols to chiral (E)-nitroalkene 1 depending on the presence of metal catalysts at low tempertwre. The resultS indicated that the anti-form had been preferred in all cases.Modest to high diastereoselectivites have been observed in the conjugate addition of functionalized alcohols to chiral (E)-nitroalkene 1 depending on the presence of metal catalysts at low tempertwre. The resultS indicated that the anti-form had been preferred in all cases.

关 键 词：DIASTEREOSELECTIVITY michael addition ALCOHOLS catalysts 

分 类 号：O621[理学—有机化学]