Scientific Research Project of General Universities in Guangdong Province(2023KTSCX036);Science and Technology Planning Program of Zhanjiang(2023B01015)for support.
Ketenimine zwitterionic salt(KZS),a novel and stable ketenimine precursor,is still underexplored in the realm of chemical synthesis.In this study,we demonstrate the transformation of pyrrole derivatives through the cy...
supported by the National Key Research and Development Program of China(No.2022YFF0709803);Natural Science Foundation of Beijing Municipality(No.2202041);the High Performance Computing Platform of Beijing University of Chemical Technology(BUCT).
The reductive lactonization strategy provides an efficient access to diastereoenriched polycyclicγ-lactones.However,it is still a formidable challenge to develop an efficient and versatile protocol with excellent lev...
the National Natural Science Foundation of China(22071112 and 22275098);the Project of State Key Laboratory of Organic Electronics and Information Displays,Nanjing University of Posts and Telecommunications(GDX2022010005 and GZR2022010011);the Postgraduate Technology&Practice Innovation Program of Jiangsu Province(KYCX22_0902).
To address the stereoselective synthesis challenge inπ-stacked grids with four chiral centers,we utilized coplanar and highly rigid 11,12-dihydroindeno[2,1-a]fluorene-11,12-diol and 2,2'-bithiophene as synthons,emplo...
supported by the Natural Science Foundation of Zhejiang Province(LZ20B020001 and LY23B020004);the Ten Thousand Talents Plan of Zhejiang Province(2020R52021);the Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang Province(2022R01007);the National Natural Science Foundation of China(22371262,22071218,and 22203076).
Comprehensive Summary A visible light photocatalytic[3+2]cycloaddition of alkynes with readily accessible organic iodides as the C3 synthon is developed herein.By merging halogen atom transfer(XAT)and hydrogen atom tr...
supported by the National Natural Science Foundation of China(22071028,21921003).
Stereoselective synthesis of multi-substituted cyclobutanes with different substituents is still a daunting challenge in organic synthesis.We report here a practical and facile approach to synthesizing all-trans 2,3,4...
the National Key R&D Program of China(grant no.2021YFA1500200);the National Natural Science Foundation of China(grant nos.92056108 and 92256303)for financial support.
A distinct class of C1-symmetric N-heterocyclic carbene(NHC)ligands possessing a chiral fused tetrahydroquinoline ring and a chiral N-arylmethyl group was designed and synthesized via an asymmetric catalytic synthesis...
financial support from the National Natural Science Foundation of China (Nos. 21871112 and 21971090)。
A new organocatalytic double annulation cascade involving scission/recombination of N-O bonds of nitrones is reported for the first time, and used to produce a range of hitherto unprecedented tricyclic bridged-fused b...
This work was supported by the National Natural Science Foundation of China(22177060);the Young Scholars Program of Shandong University(2018WLJH41);the Central Government Guide Local Science and Technology Development Funds(No.YDZX20203700002579).
Here we report a systematic investigation on the stereodirecting effects of a 4-O-ortho-cyanobenzyl ether(oBCN)group with a glucopyranosyi donor.Experimental studies revealed that the glycosylation reactions using thi...
We are grateful to the National Key Research and Development Program(2021YFC2102700);the National Natural Science Foundation of China(22077054,22078127);the National First-Class Discipline Program of Light Industry Technology and Engineering(LITE2018-07);Program of Introducing Talents of Discipline to Universities(111-2-06)for the financial support of this research.
l-Threonine transaldolase could catalyze the transaldolation of l-threonine and aldehyde to generateβ-hydroxy-α-amino acids with high diastereoselectivity.A novel l-threonine transaldolase(PmLTTA)was identified from...
We appreciatethe National Natural Science Foundation of China(Nos.21921002,22177082);the Ministry of Science and Technology of China(2017ZX09101003-005-004)for financial support.
Comprehensive Summary An efficient synthesis of a complex tetrasaccharide fragment 1 structurally related to rhamnogalacturonan ll side chain A has been accomplished through a stepwise glycosylation strategy.Challenge...