Financial support from the NSFC(22071035);Natural Science Foundation of Guangxi(2023GXNSFDA026025);Guangxi Science and Technology Plan Project(AD23026046);Graduate Innovation Training Program of Guangxi(YCSW2024160);Natural Science Foundation of Sichuan(2023NSFSC1087);Guangxi Bagui Young Scholar is greatly appreciated.
We described a Yb(OTf)_(3) combined with Pybox ligand catalyzed asymmetric[3+3]cycloaddition of N-vinyl cinnamaldehyde nitrones with activated cyclopropanes to prepare various functionalized 1,2-oxazines in 24%—95% y...
financial support from the National Natural Science Foundation of China (Nos. 21871112 and 21971090)。
A new organocatalytic double annulation cascade involving scission/recombination of N-O bonds of nitrones is reported for the first time, and used to produce a range of hitherto unprecedented tricyclic bridged-fused b...
the National Key R&D Program of China 2021YFF0701600);the National Natural Science Foundation of China(22031004,21921003,21801078,22071060);Shanghai Municipal Education Commission(20212308).
A highly enantioselective gold-catalyzed intermolecular[3+2]cycloaddition of N-allenamides with nitrones was realized by the application of Ming-Phos M6 as a chiral ligand.Both enantiomers of the cycloadducts with opp...
We are grateful to the National Natural Science Foundation of China (21425205), Ministry of Education of China, Ying Tung Education Foundation (121014) for financial support.
A gold(I)-catalyzed highly diastereo- and enantioselective intermolecular cycloaddition of oxime ethers with nitrones under mild conditions was developed, which provides an facile access to optically pure highly sub...
A [3+3] formal cycloaddition reaction between in situ formed azaoxyallyl cations and nitrones from isatins has been developed, furnishing a spectrum of spiro[1,2,4-oxadiazinan-5-one]oxindoles in good to excellent yie...
Benzohydroxamic acid reacts with dimethyl acetylenedicarboxylate in the presence of 10 mol% NaOAc to gen- erate (E)-N-(1,4-dimethoxy-l,4-dioxobutan-2-ylidene)-l-phenylcarboxamide oxide in good-to-excellent yield i...
The behaviour of cyanothioacetamide 1 and the acetonitrile derivatives 6 and 10, respectively, towards the nitrones 2a-i induced by free solar thermal energy is reported. Structures and reaction mechanisms are also di...
support from National Natural Science Foundation of China(No.20962017) ;the Natural Science Foundation of Gansu Province,China(No.2007GS03630)
α-Aryl nitrone are one of the most useful kinds of nitrones and have been extensively explored in recent years.However,the sugar moieties have not been introduced into these molecules before.We presented here an effi...
The dipolar cycloaddition reaction of allenyl perfluoroalkyl sulfones (1) to nitrones (2) was described. Unlike nonfluorine-containing allenyl sulfones, 1 reacted readily with 2 in ether at room temperatttre and u...
the National Natural Science Foundation of China (No. 20172065).
Dipolar cycloaddition reactions of ethyl 2-hydropolyfluoroalk-2-enoates (1) with some nitrones were de-scribed. The reaction of 3,4-dihydroisoquinoline N-oxide (2) with 1 took place readily in methylene chloride at ro...