~1H/~2H and ^(32)S/^(33)S isotope effect in the electron transfer reaction of thianthrene and its radical cation  

作　　者：刘中立 吕建明 杨立 陈平 王锡禄 刘有成 

机构地区：[1]State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China

出　　处：《Science China Chemistry》1995年第3期273-279,共7页中国科学（化学英文版）

基　　金：Project supported by the National Natural Science Foundation of China.

摘　　要：Significant 1H/2H and 32S/ 33S isotope effect has been found in the electron transfer reaction of thianthrene and its radical cation perchlorate. This effect may be used to establish a new effective approach to isotope enrichment.Significant 1H/2H and 32S/ 33S isotope effect has been found in the electron transfer reaction of thianthrene and its radical cation perchlorate. This effect may be used to establish a new effective approach to isotope enrichment.

关 键 词：RADICAL CATION ELECTRON TRANSFER ISOTOPE effect. 

分 类 号：O626[理学—有机化学]